53163-41-0

Basic information

• Product Name: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate
• Synonyms: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate
• CAS NO: 53163-41-0
• Molecular Weight: 282.423
• Mol File: 53163-41-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate(53163-41-0)
• EPA Substance Registry System: ((1S,2R,4aS,8aS)-2-hydroxy-2,5,5,8a-tetramethyldecahydronaphthalen-1-yl)methyl acetate(53163-41-0)

Safety Data

• Hazardous Substances Data: 53163-41-0(Hazardous Substances Data)

Upstream product

• 4128-17-0 (2E,6E)-farnesyl acetate 

Downstream Products

• 95138-34-4 11-(4-nitro-benzoyloxy)-drim-7-ene 

Relevant articles and documents

Superacidic low-temperature cyclization of terpenols and their acetates

The superacidic low-temperature cyclization of terpenols and their acetates be fluorosulfonic acid represents a highly efficient chemo- and structurally selective and stereospecific process.Homoallylic alcohols (α-isomers of cycloterpenols) are the products of cyclization of terpenols; the configuration of the hydroxymethyl group in the products is predetermined by the configuration of the allylic double bond in aliphatic or partially cyclized precursors.The cyclization of terpenyl acetates yields monoacetates of fully cyclized diastereomeric primary-tertiary γ-diols.Their stereochemistry also depends on the configuration of the allylic double bond in the starting substrates. - Key words: terpenols; terpenyl acetates; cyclization, fluorosulfonic acid, drimanes, isoagathanes, scarlanes.

CYCLIZATION OF ACYCLIC ISOPRENOIDS V REARRANGEMENT OF STEREOISOMERIC FARNESOLS AND NEROLIDOLS IN SUPERACIDS

The cyclization of 2,3-trans- and -cis-farnesols in superacids is structurally selective and stereospecific, giving drimenol and epidrimenol respectively.Depending on the reaction conditions, trans- and cis-nerolidols undergo carbo- or hetero-cyclization, to give in the first case tricyclic bridged hydrocarbons with a novel skeleton, and in the second case a 2-oxabicyclodecane.