53291-31-9

Basic information

• Product Name: Benzenesulfonothioic acid, 4-methyl-, S-(1-methylethyl) ester
• CAS NO: 53291-31-9
• Molecular Formula: C10H14O2S2
• Molecular Weight: 230.352
• Mol File: 53291-31-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzenesulfonothioic acid, 4-methyl-, S-(1-methylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonothioic acid, 4-methyl-, S-(1-methylethyl) ester(53291-31-9)
• EPA Substance Registry System: Benzenesulfonothioic acid, 4-methyl-, S-(1-methylethyl) ester(53291-31-9)

Safety Data

• Hazardous Substances Data: 53291-31-9(Hazardous Substances Data)

Upstream product

• 4253-89-8 diisopropyl sulfide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 3753-27-3 sodium 4-methylbenzenesulfonothioate 
• 75-26-3 isopropyl bromide 
• 1950-69-2 toluene-p-sulfonyl bromide 
• 75-33-2 2-propanethiol 
• 75-30-9 2-iodo-propane 
• 28519-50-8 potassium thiotosylate 

Downstream Products

• 1008769-70-7 isopropyl 4-methoxycarbonylphenyl sulfide 
• 55055-69-1 3-hydroxy-2-(isopropylthio)-5,5-dimethyl-2-cyclohexen-1-one 

Relevant articles and documents

Enantioselective Copper-Catalyzed Electrophilic Sulfenylation of Cyclic Imino Esters

Herein we report an enantioselective sulfenylation of cyclic imino esters with the efficient and versatile sulfenylation reagent S-alkyl 4-methylbenzenesulfonothioates. By utilizing the Cu/tBu-Phosferrox catalytic system, we can assemble diverse S-alkyl groups into the cyclic imino esters under mild conditions in good yields and with excellent enantioselectivities. Remarkably, this method demonstrates a high tolerance of diverse functional groups and proves to be applicable in the late-stage functionalization of pharmaceuticals.

A mild and facile synthesis of aryl and alkenyl sulfides via copper-catalyzed deborylthiolation of organoborons with thiosulfonates

An efficient deborylthiolation of aryl- and alkenylborons with thiosulfonates has been achieved under mild conditions using a copper catalyst. All steps of the experimental process were free from unpleasant odors. The mild reaction conditions as well as ready availability of boron compounds and thiosulfonates enabled easy access to an array of sulfides, including those bearing sensitive functional groups.

MUTILIN DERIVATIVE HAVING HETEROCYCLIC AROMATIC RING CARBOXYLIC ACID STRUCTURE IN SUBSTITUENT AT 14-POSITION

To provide a novel mutilin derivative having a substitution at the 14-position, which is a novel mutilin analogue exhibiting a potent and broad antimicrobial action against Gram-positive bacteria and Gram-negative bacteria including various drug-resistant bacteria, and which is expected to be useful as an agent for treating infectious diseases. A mutilin derivative represented by the following general formula (1): or a pharmaceutically acceptable addition salt thereof.