53348-04-2

Basic information

• Product Name: 9,10-DIAMINOPHENANTHRENE
• Synonyms: 9,10-PHENANTHRENEDIAMINE;9,10-DIAMINOPHENANTHRENE;phenanthrene-9,10-diylamine;Phenanthrene-9,10-diamine;Einecs 258-490-9;9,10-Diaminophenanthrene 97%
• CAS NO: 53348-04-2
• Molecular Formula: C₁₄H₁₂N₂
• Molecular Weight: 208.26
• EINECS: 258-490-9
• Mol File: 53348-04-2.mol
• Article Data: 3

Chemical Properties

• Melting Point: 164-166 °C(lit.)
• Boiling Point: 457.6 °C at 760 mmHg
• Flash Point: 276.6 °C
• Appearance: /
• Density: 1.283g/cm³
• Vapor Pressure: 1.47E-08mmHg at 25°C
• Refractive Index: 1.816
• Storage Temp.: 2-8°C
• PKA: 5.15±0.30(Predicted)
• CAS DataBase Reference: 9,10-DIAMINOPHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-DIAMINOPHENANTHRENE(53348-04-2)
• EPA Substance Registry System: 9,10-DIAMINOPHENANTHRENE(53348-04-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 53348-04-2(Hazardous Substances Data)

Usage

General Description

9,10-Diaminophenanthrene is a polycyclic aromatic compound consisting of a phenanthrene backbone with two amino groups located at the 9 and 10 positions. It is commonly used as a precursor in the synthesis of various organic compounds and dyes. This chemical exhibits strong fluorescence and has been studied for its potential application in organic light-emitting diodes (OLEDs) and optoelectronic devices. 9,10-Diaminophenanthrene also possesses antioxidant properties and has shown potential as a therapeutic agent in the treatment of oxidative stress-related diseases. Furthermore, it has been investigated for its use in organic synthesis, pharmaceuticals, and materials science due to its unique structure and reactivity.

InChI:InChI=1/C14H12N2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H,15-16H2

Upstream product

• 14090-76-7 phenanthrene-9,10-dione dioxime 
• 7647-01-0 hydrogenchloride 
• 15810-15-8 9,10‐dibromophenanthrene 

Downstream Products

• 5768-84-3 phenanthro[9,10-g]pteridine-11,13(10H,12H)-dione 
• 60190-76-3 C₅₀H₃₈N₂P₂ 
• 179550-51-7 N,N,N',N'-tetrakis(4-biphenylyl)-9,10-phenanthrylenediamine 
• 910612-55-4 14H-phenanthro[9',10':4,5]imidazo[2,1-a]isoindol-14-one 
• 859798-47-3 2-phenyldibenzo[f,h]quinoxaline 
• 143252-32-8 benzyltriphenylphosphonium tetrachloro(phenanthrene-9,10-diamine)chromate(III) 
• 103307-09-1 2,3-diphenyldibenzoquinoxaline 

Relevant articles and documents

Organic electroluminescence material containing phenanthrene structure and organic luminescence device thereof

The invention provides an organic electroluminescence material containing a phenanthrene structure and an organic luminescence device thereof, and belongs to the technical field of organic photoelectric materials. The structure of the organic electroluminescence material containing the phenanthrene structure contains the phenanthrene ring structure, wherein the phenanthrene ring structure is a blue ray structure which is excellent in performance and has a higher triplet state energy level and a wider energy gap, and in molecules, through connection with benzimidazole groups, the electron transportation capability of the blue ray main structure is enhanced, so that carrier transportation is balanced. Compared with the prior art, the material has the advantages that the material is applied to the organic luminescence device and especially used as the blue luminescence material in a luminescence layer, the luminescence efficiency is relatively high, and the driving voltage is relatively low.

Electrochromic properties of phenantrene centered EDOT polymers

A series of phenantrene centered donor-acceptor type electroactive 3,4-ethlenedioxythiophene (EDOT) monomers (EP-X) containing N, S and Se heteroatom on the bezophenantra-X-diazole acceptor unit have been synthesized by Stille coupling reaction. These monomers were electrochemically polymerized by potentiodynamic method to obtain electrochromic polymer films. Spectro-electrochemical properties were also investigated by UV-vis absorption connected with the cyclic voltammetry measurements. The polymer films exhibited a remarkable trend of visible color (yellow, orange, red) at the neutral state due to changing the central acceptor moiety. These polymer films have multielectrochromic properties by means of moderately changing the absorbance/transmittance at the visible regime upon applied positive potentials. The donor-acceptor interaction at the neutral state correlated by DFT calculations was also supported by the interesting trend in the colors of these polymers. Finally, the electrochromic performance of EP-X polymer films represented a high redox stability, reasonable contrast ratio, coloration efficiency and response times.