533902-59-9

Basic information

• Product Name: 1-[3-(but-3-enyloxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester
• Synonyms: 1-[3-(but-3-enyloxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester
• CAS NO: 533902-59-9
• Molecular Weight: 509.64
• Mol File: 533902-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[3-(but-3-enyloxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[3-(but-3-enyloxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester(533902-59-9)
• EPA Substance Registry System: 1-[3-(but-3-enyloxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester(533902-59-9)

Safety Data

• Hazardous Substances Data: 533902-59-9(Hazardous Substances Data)

Upstream product

• 533902-44-2 1-[3-(tert-butyldimethylsilyloxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester 
• 533902-41-9 2-methyl-propane-2-sulfinic acid [3-(tert-butyldimethylsilyloxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]methyleneamide 
• 533902-55-5 tert-butyl-(4,5-dimethoxy-6-methoxymethyl-2-vinyltetrahydropyran-3-yloxy)dimethylsilane 
• 533902-39-5 4,5-dimethoxy-6-methoxymethyl-2-vinyltetrahydropyran-3-ol 
• 16740-98-0 tri-O-methyl-D-glucal 
• 149650-47-5 1,2-anhydro-3,4,6-tri-O-methyl-α-D-glucopyranose 
• 117983-52-5 3-buten-1-yl chloromethyl ether 
• 533902-57-7 1-(3-hydroxy-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl)-2-phenylethylcarbamic acid tert-butyl ester 

Downstream Products

• 533902-49-7 1-[4,5-dimethoxy-6-methoxymethyl-3-(tetrahydrofuran-2-yloxymethoxy)tetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester 
• 533902-62-4 1-[3-(4-hydroxybutoxymethoxy)-4,5-dimethoxy-6-methoxymethyltetrahydropyran-2-yl]-2-phenylethylcarbamic acid tert-butyl ester 

Relevant articles and documents

An oxidative entry into the amido trioxadecalin ring system.

The amido trioxadecalin ring system is a key structural component of the architecturally interesting anticancer and immunosuppressive agents of the mycalamide, theopederin, and onnamide families of natural products. We report a new entry into this structure in which a mixed acetal serves as a surrogate for a formaldehyde hemiacetal in an addition to an oxidatively generated acyliminium ion. The stereochemical outcome of this process can be explained by the conformational preferences of the product ring system. [reaction: see text]