53567-64-9

Basic information

• Product Name: (1R^*,5R^*)-p-1,8-menthadien-6-ylamine
• CAS NO: 53567-64-9
• Molecular Weight: 151.252
• Mol File: 53567-64-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1R^*,5R^*)-p-1,8-menthadien-6-ylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (1R^*,5R^*)-p-1,8-menthadien-6-ylamine(53567-64-9)
• EPA Substance Registry System: (1R^*,5R^*)-p-1,8-menthadien-6-ylamine(53567-64-9)

Safety Data

• Hazardous Substances Data: 53567-64-9(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 31198-76-2 carvoxime 
• 7111-29-7 (1R-cis)-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol acetate 
• 99-48-9 5-Isopropenyl-2-methyl-cyclohex-2-enol 
• 80124-30-7 oxime (4S)-4-isopropenyl-1-methylcyclohex-1-en-6-one 
• 97-42-7 carvyl acetate 
• 2051-55-0 (S)-p-mentha-6,8-dien-2-one-(Z)-oxime 
• 65877-16-9 (R)-p-mentha-6,8-dien-2-one-(Z)-oxime 

Downstream Products

• 53567-68-3 N_.N'-Biscaroylthioharnstoff 
• 62311-60-8 N-<(1R^*,5R^*)-carvyl>benzamide 
• 53567-65-0 Caroylisothiocyanat 
• 62311-60-8 N-p-mentha-6,8-dien-2-yl-benzamide 

Relevant articles and documents

Direct amination of bio-alcohols using ammonia

A slightly adapted catalyst system has been successfully applied in the direct amination of primary and secondary alcohols. Moreover, the applicability to diols has been shown, giving high selectivity towards the primary diamines. It was found that the Ru/P ratio as well as the amount of ammonia used are highly important in this system, especially for higher substrate loadings. The catalyst was employed on a larger batch scale for the conversion of isomannide to the corresponding diamine. Additionally, it was shown that the catalyst is stable for at least six consecutive runs. No significant loss of activity and selectivity was observed.

PALLADIUM(0) CATALYZED AZIDATION AND AMINATION OF ALLYL ACETATES. SELECTIVE SYNTHESIS OF ALLYL AZIDES AND PRIMARY ALLYLAMINES

Palladium catalyzed reaction of allyl acetates with azide ion gives allyl azides, which are readily converted into the corresponding primary allylamines upon treatment with PPh3/NaOH.