53588-13-9

Basic information

• Product Name: Phenylsulfonyl-4-methyl-3-acetoxy-1-buten-2
• Synonyms: Phenylsulfonyl-4-methyl-3-acetoxy-1-buten-2
• CAS NO: 53588-13-9
• Molecular Weight: 268.334
• Mol File: 53588-13-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenylsulfonyl-4-methyl-3-acetoxy-1-buten-2(CAS DataBase Reference)
• NIST Chemistry Reference: Phenylsulfonyl-4-methyl-3-acetoxy-1-buten-2(53588-13-9)
• EPA Substance Registry System: Phenylsulfonyl-4-methyl-3-acetoxy-1-buten-2(53588-13-9)

Safety Data

• Hazardous Substances Data: 53588-13-9(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 
• 98-09-9 benzenesulfonyl chloride 
• 38872-49-0 4-acetoxy-1-chloro-2-methyl-2-butene 
• 873-55-2 sodium benzenesulfonate 
• 5829-79-8 (E)-4-chloro-2-methyl-1-phenylsulfonyl-2-butene 
• 127-09-3 sodium acetate 

Downstream Products

• 80283-59-6 (E)-((3-methylbuta-1,3-dien-1-yl)sulfonyl)benzene 
• 26157-20-0 2-methyl-1-(phenylsulfonyl)-1,3-butadiene 

Relevant articles and documents

FACILE ROUTE TO 1-PHOSPHORYL- AND 1-SULFONYL-1,3-DIENES VIA PALLADIUM-CATALYZED ELIMINATION OF ALLYLIC ACETATES

The palladium(II)-catalyzed chloroacetoxylation of 1,3-dienes is employed to prepare 1-chloro-4-acetoxy-2-alkenes which are then transformed into 1-phosphoryl- or 1-sulfonyl-4-acetoxy-2-alkenes respectively.Elimination of acetate is promoted by palladium(