535975-23-6

Basic information

• Product Name: dimethyl(phenyl)(3,3,3-trifluoropropan-1-en-2-yl)silane
• Synonyms: dimethyl(phenyl)(3,3,3-trifluoropropan-1-en-2-yl)silane
• CAS NO: 535975-23-6
• Molecular Weight: 230.305
• Mol File: 535975-23-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: dimethyl(phenyl)(3,3,3-trifluoropropan-1-en-2-yl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl(phenyl)(3,3,3-trifluoropropan-1-en-2-yl)silane(535975-23-6)
• EPA Substance Registry System: dimethyl(phenyl)(3,3,3-trifluoropropan-1-en-2-yl)silane(535975-23-6)

Safety Data

• Hazardous Substances Data: 535975-23-6(Hazardous Substances Data)

Upstream product

• 754-12-1 2,3,3,3-tetrafluoro-propene 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 1514-82-5 2-bromo-3,3,3-trifluoropropene 
• 768-33-2 phenyldimethylsilyl chloride 

Downstream Products

• 535975-28-1 (2,2-difluoro-1-undecylvinyl)dimethylphenylsilane 
• 535975-30-5 [2,2-difluoro-1-(2-phenyl-1,3-dithian-2-ylmethyl)vinyl]dimethylphenylsilane 
• 535975-35-0 [2-(dimethylphenylsilyl)-3,3-difluoroallyl]diisopropylamine 
• 1433609-23-4 N’-[3,3-difluoro-2-(dimethylphenylsilyl)prop-2-en-1-yl]-N’-phenyl-p-toluenesulfonohydrazide 
• 1433609-17-6 N’-[3,3-difluoro-2-(dimethylphenylsilyl)prop-2-en-1-yl]-N’-tert-butoxycarbonyl-p-toluenesulfonohydrazide 
• 899437-07-1 N-{o-[3,3-difluoro-2-(dimethylphenylsilyl)prop-2-en-1-yl]phenyl}-p-toluenesulfonamide 
• 899437-08-2 3-fluoro-3-(dimethylphenylsilyl)-1-(p-toluenesulfonyl)-1,4-dihydroquinoline 
• 899437-05-9 3,3-difluoro-[o-(2-dimethylphenylsilyl)prop-2-en-1-yl]aniline 

Relevant articles and documents

A novel synthesis of functionalized 1,1-difluoro-1-alkenes via isolable 2,2-difluorovinylsilanes

Various 1,1-difluoro-1-alkenes such as monosubstituted 1,1-difluoro-1-alkenes, 2-bromo-1,1-difluoro-1-alkenes, and 1,1-difluoro-3-hydroxy-1-alkenes are prepared in two simple steps from 1-trifluoromethylvinylsilane: (i) its SN2′ reaction with nucleophiles to construct 2,2-difluorovinylsilanes and (ii) the subsequent substitution of electrophiles for the vinylic silyl group.

METHOD FOR PRODUCING SUBSTITUTED OLEFIN COMPOUND

PROBLEM TO BE SOLVED: To provide a new method for producing a substituted olefin compound, in particular, a new method for producing a fluorine-containing olefin substituted with a boron-containing group or a silicon-containing group. SOLUTION: There is provided a method for producing a compound represented by the formula (1), which comprises a step of reacting a fluorinated olefin with a compound represented by the formula (3).[R1 to R3 represent H, F, an organic group or the like; RX represents -BX2 or -SiX3; X represents H, a halogen or an organic group; provided that X may form a ring together with adjacent B or Si; Y1 and Y2 each independently represent OH or an alkoxy group; provided that Y1 and Y2 may form a ring together with adjacent B.] SELECTED DRAWING: None COPYRIGHT: (C)2017,JPO&INPIT