53627-10-4Relevant articles and documents
Trichloromethanesulfonyl chloride: A chlorinating reagent for aldehydes
Jimeno, Ciril,Cao, Lidong,Renaud, Philippe
, p. 1251 - 1255 (2016/02/19)
Trichloromethanesulfonyl chloride (CCl3SO2Cl), a commercially available reagent, has been found to perform efficiently in the α-chlorination of aldehydes, including its catalytic asymmetric version, under very mild reaction conditions. Under our reaction conditions, this compound outperforms typical chlorinating reagents for organic synthesis, facilitates workup and purification of the product, and minimizes the formation of toxic, chlorinated organic waste.
Synthesis of 1,1-bisphosphono-2-aza-1,3-dienes, a new class of electron-deficient azadienes
Masschelein, Kurt G.R.,Stevens, Christian V.
, p. 4336 - 4338 (2008/09/21)
1,1-Bisphosphono-2-aza-1,3-dienes are formed by 1,4-dehydrohalogenation of the corresponding N-(bisphosphonomethyl)-α-haloimines in moderate to good yields. The precursors could be formed by condensation of bisphosphono-amines and the corresponding α-haloaldehydes.
The Regiochemistry of the Radical Addition of N-Chloroamides to Enol Ethers
Caron, Gilles,Lessard, Jean
, p. 8039 - 8058 (2007/10/02)
The orientation of the radical addition of N-chloroamides (ZCONHCl) to enol ethers was studied as a function of Z and the enol ether structure and compared with the orientation of radical addition of thioacetic acid and the orientation of typical electrop