538-39-6Relevant articles and documents
Comparative activity of aryl, alkyl, and cycloalkyl halides in the suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium
Kras'Ko,Zlotskii,Boyarskii
, p. 2541 - 2546 (2015)
Relative activity of halogenated arenes, alkanes, and alkanes in the Suzuki reaction catalyzed with acyclic diaminocarbene complex of palladium has been investigated. Under all the investigated conditions, 4-iodoanisole has been more active than the alkyl
Carbon-Carbon σ-Bond Transfer Hydrogenation with DMF Catalyzed by Cobalt Porphyrins
Tam, Chun Meng,To, Ching Tat,Chan, Kin Shing
, p. 2174 - 2177 (2016)
Cobalt porphyrins were found to catalyze the transfer hydrogenation of the carbon-carbon σ bond of [2.2]paracyclophane (PCP) with the solvent DMF serving as the hydrogenating agent. Successful trapping experiments with benzene solvent and the kinetic isot
NMR and computational studies of the chemical reduction of [2.2]paracyclophane: Formation of dianionic p-xylenyl oligomers
Gridnev, Ilya D.,Pichierri, Fabio
, p. 150 - 151 (2004)
Reaction of [2.2]paracyclophane with K/Na alloy in THF gives a p-xylylenyl dianion together with its dimer and trimer which are relatively stable at low temperatures; at ambient temperatures further polymerization takes place.
Iridium-catalyzed carbon-Carbon σ-bond hydrogenation with water: Rate enhancement with iridium hydride
To, Ching Tat,Tam, Chun Meng,Chan, Kin Shing
, p. 4333 - 4336 (2015)
Iridium porphyrins were found to be good catalysts for the carbon-carbon σ-bond hydrogenation of [2.2]paracyclophane using water in neutral conditions. Mechanistic investigations reveal the promoting effects of iridium porphyrin hydride, IrIII(
Mixed Alkyl/Aryl Diphos Ligands for Iron-Catalyzed Negishi and Kumada Cross Coupling Towards the Synthesis of Diarylmethane
Ma, Xufeng,Wang, Han,Liu, Yao,Zhao, Xing,Zhang, Jun
, p. 5134 - 5140 (2021/11/16)
Mixed alkyl/aryl diphos ligands have been prepared and their application in iron-catalyzed cross coupling of benzylic chlorides with diaryl zinc (Negishi) or aryl Grignard reagents (Kumada) towards the synthesis of diarylmethane has been evaluated. The iron?diphos catalytic system exhibited the enhanced activity and selectivity in the two coupling reactions. The electron-rich mixed PPh2/PCy2 ligands outperformed their symmetrical PPh2 congeners, and led to decreased homocoupling byproduct formation. It indicates that the electronic effect of the ligands plays an important role in the catalytic performance. The Fe catalyst supported by L8 bearing an electron-rich PCy2 substituent and a sterically demanding tert-butyl on ethene backbone exhibited the best catalytic performance and good functional group tolerance in the two cross coupling reactions.
Aerobic cross-dehydrogenative couplings of N-heteroarenes with toluene derivatives at room temperature
Chen, Yufeng,Deng, Guo-Jun,Huang, Huawen,Sun, Zhaozhao,Wang, Qiao-Lin
supporting information, p. 7790 - 7795 (2021/10/12)
A set of mild aerobic cross-dehydrogenative couplings of N-heteroarenes with the benzylic C(sp3)-H bond has been achieved by using visible-light-induced photocatalysis. This approach was found to provide a sustainable alternative to Minisci benzylation reactions using readily accessible toluene derivatives as benzylating agents. The unique combination of photocatalysis, bromo radical mediation, and aerobic oxidation proved to be the key for the success of the transformation. Mechanistic studies revealed the feasibility of both oxidative and reductive quenching of the excited photocatalyst in the initial step.