53828-74-3

Basic information

• Product Name: Morpholine, 4-(3-methyl-1-butenyl)- (9CI)
• Synonyms: Morpholine, 4-(3-methyl-1-butenyl)- (9CI)
• CAS NO: 53828-74-3
• Molecular Formula: C₉H₁₇NO
• Molecular Weight: 155.24
• Mol File: 53828-74-3.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 228.4°C at 760 mmHg
• Flash Point: 66°C
• Appearance: /
• Density: 0.983g/cm³
• Vapor Pressure: 0.0736mmHg at 25°C
• Refractive Index: 1.527
• CAS DataBase Reference: Morpholine, 4-(3-methyl-1-butenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 4-(3-methyl-1-butenyl)- (9CI)(53828-74-3)
• EPA Substance Registry System: Morpholine, 4-(3-methyl-1-butenyl)- (9CI)(53828-74-3)

Safety Data

• Hazardous Substances Data: 53828-74-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H17NO/c1-9(2)3-4-10-5-7-11-8-6-10/h3-4,9H,5-8H2,1-2H3/b4-3+

Upstream product

• 110-91-8 morpholine 
• 107-13-1 acrylonitrile 
• 78-79-5 isoprene 
• 590-86-3 isovaleraldehyde 

Downstream Products

• 91083-10-2 R*,R*-[α-(Phenylphosphino)isovaleraldehyde]pentacarbonyltungsten 

Relevant articles and documents

Synthesis of Chromone-Containing Allylmorpholines through a Morita–Baylis–Hillman-Type Reaction

The first example of an unusual addition of chromone-substituted acrylic acid to enamines is described. The process shows high versatility concerning both enamines and chromones. The reaction is catalyzed by tertiary amines and is highly likely of Morita–

Process for the manufacture of 2,5-disubstituted pyridines

The present invention concerns a process for the preparation of a 2,5 disubstituted pyridine of the formula (I) which comprises the steps of a) reacting a compound of the formula (II)R1-CH=CH-R2(II)with an acrylic compound of the formula (III) to form a c

Synthesis of α-Cyanoenamines by Cyanation of α-Bromoimmonium Bromides and Dehydrobromination of β-Bromo-α-(dialkylamino)nitriles

The reaction of α-bromoimmonium bromides 4 with potassium cyanide in dimethylformamide gave rise to β-bromo-α-(dialkylamino)nitriles 5, which were dehydrobrominated in various base solvent systems to afford (E)- and (Z)-α-cyanoenamines 2.An adaption of a previously published preparation of α-cyanoenamines starting from aldehydes via enamines led to an improved, efficient and fast synthesis of the title compounds.