53859-89-5

Basic information

• Product Name: Diallyl ketone
• Synonyms: 1,6-Heptadien-4-one;Diallyl ketone;1,6-heptadien-4-one:diallyl ketone
• CAS NO: 53859-89-5
• Molecular Formula: C₇H₁₀O
• Molecular Weight: 110.1537
• Mol File: 53859-89-5.mol
• Article Data: 6

Chemical Properties

• Melting Point: 83-84℃
• Boiling Point: 40℃ (10 Torr)
• Appearance: /
• Density: 0.838±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Diallyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: Diallyl ketone(53859-89-5)
• EPA Substance Registry System: Diallyl ketone(53859-89-5)

Safety Data

• Hazardous Substances Data: 53859-89-5(Hazardous Substances Data)

Usage

General Description

Diallyl ketone is a chemical compound with the formula C6H10O. It is a colorless to yellowish liquid with a strong, onion-like odor. Diallyl ketone is primarily used as a flavoring agent in food and beverages, providing a pungent, garlic-like taste and odor. It is also used as a flavor additive in the production of certain alcoholic beverages and as a fragrance in perfumes and cosmetics. Diallyl ketone is considered toxic if ingested or inhaled in large amounts, and it can cause irritation to the skin, eyes, and respiratory system. Additionally, it has been found to have potential carcinogenic and mutagenic properties. Therefore, it is important to handle and use diallyl ketone with caution and in accordance with safety regulations.

Upstream product

• 2883-45-6 1, 6-heptadien-4-ol 
• 92371-14-7 5-allyl-5-hydroxy-2,4,4-trimethyl-oct-7-en-3-one 
• 107-10-8 propylamine 
• 134465-76-2 (+/-)-1,2,3,4-tetrahydro-8-methoxy-2-oxo-1-(2-propenyl)naphthalene 

Downstream Products

• 120-92-3 cyclopentanone 
• 1262795-82-3 C₅₈H₆₀N₄O₂₀S₂ 
• 1262795-81-2 C₅₄H₅₆N₄O₁₆S₂ 
• 1262795-77-6 C₃₀H₃₂N₂O₁₀S 
• 1262795-76-5 C₂₈H₃₀N₂O₈S 
• 1262795-75-4 C₂₉H₃₀N₂O₁₀S 
• 1262795-74-3 C₂₇H₂₈N₂O₈S 
• 1262795-73-2 C₂₆H₂₈N₂O₁₀S 
• 1262795-72-1 C₂₄H₂₆N₂O₈S 
• 1262795-71-0 C₁₇H₂₁BrN₂O₆S 
• 915149-82-5 6,6-dibromobicyclo[3.1.0]hexan-3-one (2R,3R)-2,3-dibenzylethylene ketal 
• 915149-80-3 (2R,3R)-2,3-dibenzyl-1,4-dioxaspiro[4.4]non-7-ene 
• 915149-78-9 (2R,3R)-2,2-diallyl-4,5-dibenzyl-[1,3]dioxolane 
• 14320-37-7 3-Cyclopentenon 

Relevant articles and documents

OXIDATION OF HOMOALLYL ALCOHOLS

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Perfluoroalkylated Calix[4]pyrroles: Fluoride Ion Extraction from an Aqueous Medium

Octaalkenyl calix[4]pyrrole ((CH2=CH(CH2)2)8C4P) is highly useful for the postfunctionalization of different calix[4]pyrroles with desired functionalities. Functionalization with perfluoroalkyl chains [CF3(CF2)n; Rfn] gave perfluoroalkyl calix[4]pyrroles (Rfn(CH2)4)8C4P; n=6, 8), having >60 % fluorine content, which created a hydrophobic environment inside the calix[4]pyrrole cavity and recognized fluoride and chloride ions in solution as well as in the solid state. The fluoride ion is extracted efficiently from aqueous CsF and TBAF solutions by using (Rf6(CH2)4)8C4P, as droplets. The fluorinated chain generated a hydrophobic environment which broke the hydration shell associated with the anion and separated out fluoride ions as droplets from aqueous medium. Furthermore, the fluoride ions competitively replaced chloride ions from the (Rf6(CH2)4)8C4P cavity.

Concise assembly of the polycyclic frameworks associated with the hapalindole and fischerindole alkaloids

Reaction of N-methylindole (4) with 6,6-dibromobicyclo[3.1.0]hexane (5) in the presence of silver tetrafluoroborate affords conjugate 7 in 67% yield. This product can be readily elaborated to compounds 12b and 13b which embody the polycyclic frameworks as