54020-52-9Relevant articles and documents
Enantio- and Diastereoselective Catalysis of Addition Reaction of Allylic Silanes and Stannanes to Glyoxylates by Binaphthol-derived Titanium Complex
Aoki, Seiichi,Mikami, Koichi,Terada, Masahiro,Nakai, Takeshi
, p. 1783 - 1792 (1993)
Chiral titanium complex (1), prepared in situ from optically pure binaphthol and diisopropoxytitanium dihalide in the presence of molecular sieves, is shown to catalyze the addition reactions of crotylsilanes and -stannanes to glyoxylates to afford (syn)-α-hydroxy-β-methyl esters in highly scalemic forms with high diastereoselectivity.Key Words: Asymmetric catalysis; Enantiocontrol; Diastereocontrol; Allylic silane; Allylic stannane; Carbonyl-addition reaction; Carbonyl-enereaction; Glyoxylate; Binaphthol-derived titanium dihalide; Chiral titanium complex
Ortho Ester Claisen Rearrangements Using Trimethyl Methoxyorthoacetate
Daub, G. William,Teramura, Douglas H.,Bryant, Kevin E.,Bruch, Mark T.
, p. 1485 - 1486 (2007/10/02)
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