54051-41-1

Basic information

• Product Name: Piperidine, 1-(1,1-dimethylethoxy)-2,2,6,6-tetramethyl-
• CAS NO: 54051-41-1
• Molecular Formula: C13H27NO
• Molecular Weight: 213.363
• Mol File: 54051-41-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Piperidine, 1-(1,1-dimethylethoxy)-2,2,6,6-tetramethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 1-(1,1-dimethylethoxy)-2,2,6,6-tetramethyl-(54051-41-1)
• EPA Substance Registry System: Piperidine, 1-(1,1-dimethylethoxy)-2,2,6,6-tetramethyl-(54051-41-1)

Safety Data

• Hazardous Substances Data: 54051-41-1(Hazardous Substances Data)

Upstream product

• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 1384194-57-3 2,3-dihydro-2-tert-butyl-3-benzyl-4(1H)-quinazolinone 
• 815-24-7 Di-t-butyl ketone 

Downstream Products

• 75-65-0 tert-butyl alcohol 
• 31366-07-1 3,3-dimethyl-1-phenyl-butan-1-one 

Relevant articles and documents

Photoinduced elimination in 2,3-dihydro-2-tert -butyl-3-benzyl-4(1 h)-quinazolinone: Theoretical calculations and radical trapping using TEMPO derivatives

Photochemical irradiation of 2,3-dihydro-2-tert-butyl-3-benzyl-4(1H)- quinazolinone produced 3-benzyl-4(3H)-quinazolinone through photoinduced elimination via a radical mechanism. The use of photochemical conditions such as chloroform and UV irradiation (δ= 254 nm) got the 3-benzyl-4(3H)- quinazolinone in a high yield. Some theoretical calculations were achieved to explain the mechanism and the presence of radical intermediates was confirmed by trapping with different 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) derivatives. Georg Thieme Verlag Stuttgart · New York.