54106-41-1

Basic information

• Product Name: Ethanone, 1-[1-chloro-2-(4-methoxyphenyl)cyclohexyl]-, trans-
• CAS NO: 54106-41-1
• Molecular Formula: C15H19ClO2
• Molecular Weight: 266.768
• Mol File: 54106-41-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[1-chloro-2-(4-methoxyphenyl)cyclohexyl]-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[1-chloro-2-(4-methoxyphenyl)cyclohexyl]-, trans-(54106-41-1)
• EPA Substance Registry System: Ethanone, 1-[1-chloro-2-(4-methoxyphenyl)cyclohexyl]-, trans-(54106-41-1)

Safety Data

• Hazardous Substances Data: 54106-41-1(Hazardous Substances Data)

Upstream product

• 52839-59-5 (3R,4R)-4-(4-Methoxy-phenyl)-2-methyl-1-oxa-spiro[2.5]octane-2-carbonitrile 

Downstream Products

• 93959-06-9 1α-Methyl-2α-(4-methoxy-phenyl)-cyclohexan-1β-carbonsaeurebenzylester 
• 100-51-6 benzyl alcohol 
• 54106-42-2 1α-Methyl-2α-(4-methoxy-phenyl)-cyclohexan-1β-carbonsaeuremethylester 

Relevant articles and documents

Determination of Configurations by the Acid of Sterically Corresponding Epoxides. XI. Glycidic Nitriles. IV. Synthesis of 1α-Methyl-2α-aryl-cyclohexane-1β-carboxylic Acids from 4α-Aryl-2-methyl-1α-oxaspirooctane-2-nitriles

The opening of an epoxide ring of the C-2-isomeric glycidic nitriles 1a - b with anhydrous HCl in dry Et2O yields the corresponding chlorocyanoanhydrines 2a - b.Treatment of these chlorocyanohydrines with diluted NaOH does not give the expected α-chloroke