5413-60-5Relevant articles and documents
Stereoselective exo-addition to norbornenes of acetic acid generated from vinyl acetate in the presence of rhodium complexes
Khusnutdinov,Shchadneva,Mukhametshina
experimental part, p. 54 - 58 (2010/06/19)
Rhodium complexes catalyzed decomposition of vinyl acetate with liberation of acetic acid and subsequent stereoselective exo-addition of the latter to norbornene and its derivatives under mild conditions.
Process for making tricyclodecenyl esters
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Page/Page column 5; 6; 8, (2008/12/04)
A practical, economical process for making tricyclodecenyl esters is disclosed. After reacting a lower carboxylic acid and a dicyclopentadiene in the presence of triflic acid to form the ester, the reaction mixture is distilled in the presence of a base to isolate a fragrance-quality tricyclodecenyl ester. Adding enough base to neutralize the triflic acid enables a distillation-only purification, facilitates starting material recovery, and avoids drawbacks of a basic workup.
Production of "dicylate" perfume
Mamedov
, p. 81 - 85 (2007/10/03)
The method for producing "dicylate" - tricyclo[5,2,1,02,6]dec-3-enyl-8(9)-acetate -from acetic acid and tricyclo[5,2,1,02,6]deca-3,8-diene has been improved. The reaction is carried out at a temperature of 130-170°C and spontaneous pressure, which enables the use of strong acids as catalysts to be discarded.