54147-92-1Relevant articles and documents
Iron-Catalyzed Aerobic Dehydrogenative Kinetic Resolution of Cyclic Secondary Amines
Lu, Ran,Cao, Liya,Guan, Honghao,Liu, Lei
supporting information, p. 6318 - 6324 (2019/05/09)
A nonenzymatic iron-catalyzed dehydrogenative kinetic resolution of cyclic secondary amines using air as an oxidant has been reported. The economical and practical method is applicable to a series of cyclic benzylic amines, including 5,6-dihydrophenanthridines and 1,2-dihydroquinolines, with diverse functional groups at the α position in high yields with excellent enantioselectivities. The direct dehydrogenative kinetic resolution of advanced intermediates of bioactive molecules that are difficult to access using existing catalytic asymmetric synthetic strategy was also demonstrated.
Iron-catalyzed aryl-aryl cross-coupling reaction tolerating amides and unprotected quinolinones
Kofink, Christiane C.,Blank, Benoit,Pagano, Sandro,Goetz, Nadine,Knochel, Paul
, p. 1954 - 1956 (2008/02/07)
The iron(III)-catalyzed cross-coupling reaction between functionalized arylcopper reagents and aromatic iodides bearing an amide function or an unprotected quinolinone leads smoothly to polyfunctionalized biphenyls in excellent yields due to an intramolec
