54175-55-2Relevant articles and documents
Poly(ferrocenylsilane-block-methacrylates) via Sequential Anionic and Atom Transfer Radical Polymerization
Korczagin, Igor,Hempenius, Mark A.,Vancso, G. Julius
, p. 1686 - 1690 (2004)
A route to 2-bromoisobutyryl end-functionalized poly(ferrocenyldimethylsilane), allowing essentially quantitative end-capping was discussed. Following the formation of the organometallic block by anionic polymerization, a ruthenium-mediated controlled radical polymerization of methyl methacrylate was employed to grow the second block. Well-defined PFS-b-PMMA block copolymers with low polydispersities and controlled compositions were obtained. The use of atom transfer radical polymerization (ATRP) to form the second block implies that a wide variety of (meth)acrylic and other vinyl monomers can be used, which opens the way to novel hybrid organic-organometallic block copolymers and amphiphilic organometallic block copolymers.
FUNCTIONALIZED SILANES AND ELECTROLYTE COMPOSITIONS AND ELECTROCHEMICAL DEVICES CONTAINING THEM
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Page/Page column 28, (2016/04/26)
Described are compounds of the structure R4-a-Si-(Sp-Y)a-Zb, wherein "a" is integer from 1 to 4; "b" is an integer from 0 to (3 x a); "Z," which is absent when "b "R" or formula (II), wherein each "R" is halogen, C1-6 linear or branched alkyl, alkenyl, or alkynyl or C1-6 linear or branched halo-alkyl, halo-alkenyl, or halo-alkynyl; each "Sp" C1-15 linear or branched alkylenyl or CMS linear or branched halo-alkylenyl; and each "Y" an organic polar group. Also described are electrolyte compositions containing one or more of these compounds.