542-40-5Relevant articles and documents
Hydrophilic carotenoids: Surface properties and aggregation behavior of the potassium salt of the highly unsaturated diacid norbixin
Breukers, Stefanie,pstad, Christer L.,Sliwka, Hans-Richard,Partali, Vassilia
, p. 1741 - 1747 (2009)
The oft-claimed 'good' water solubility of the food color norbixin (3) could not be confirmed. In contrast, the potassium salt 5 of norbixin formed suitable dispersions. The surface and aggregation properties of salt 5 were investigated and compared with
NOVEL INTERMEDIATES FOR PREPARING NORBIXIN OR BIXIN ETHYL ESTER AND METHODS THEREOF
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Paragraph 0146; 0148-0152, (2020/10/13)
The present invention relates to a method for preparing a carotenoid compound, norbixin or bixin ethyl ester, from a novel intermediate compound. When using the novel intermediate compound, norbixin or bixin ethyl ester can be prepared in high yield through a simple process.
Thermal degradation kinetics of bixin in an aqueous model system
Rios, Alessandro De O.,Borsarelli, Claudio D.,Mercadante, Adriana Z.
, p. 2307 - 2311 (2007/10/03)
The kinetics of the thermal degradation of the natural cis carotenoid bixin in a water/ethanol (8:2) solution was studied as a function of temperature (70-125°C), using high-performance liquid chromatography. The curves for the decay of bixin and formation of products (e.g., di-cis and all-trans isomers and a C17 degradation compound) did not adjust well to a first-order rate law, but very good fits were obtained using a biexponential model. This mathematical modeling gave the rate constant values for the formation of the primary products from bixin, and the energy barrier for each step was obtained. The di-cis isomers were formed immediately (15 kcal/mol) together with the decay of bixin, followed by a slow consumption, indicating their role as reaction intermediates. In fact, the di-cis isomers could easily revert to bixin (Ea ≈ 3 kcal/mol) or yield the primary C17 degradation product, with an energy barrier of 6.5 kcal/mol. In turn, 24 kcal/mol was necessary for the Bix - all-trans step, explaining its slower formation.