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542-59-6

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542-59-6 Usage

Description

2-HYDROXYETHYL ACETATE is a colorless liquid with a nearly odorless smell. It is soluble in water, alcohol, ether, benzene, and toluene, and is combustible in nature.

Uses

Used in Pharmaceutical Industry:
2-HYDROXYETHYL ACETATE is used as a solvent for various pharmaceutical applications, such as the production of nitrocellulose, cellulose acetate, and camphor. Its solubility in multiple solvents makes it a versatile option for dissolving different types of compounds in the pharmaceutical sector.
Used in Cosmetics Industry:
2-HYDROXYETHYL ACETATE is used as a solvent in the cosmetics industry for the formulation of various cosmetic products. Its ability to dissolve a wide range of substances allows for the creation of stable and effective formulations.
Used in Paint and Coating Industry:
2-HYDROXYETHYL ACETATE is used as a solvent in the paint and coating industry to help dissolve and mix various components, such as resins and pigments, to create a uniform and consistent product.
Used in Adhesive Industry:
2-HYDROXYETHYL ACETATE is used as a solvent in the adhesive industry to facilitate the mixing and application of adhesive formulations. Its solubility properties enable it to dissolve various adhesive components, improving the overall performance of the final product.
Used in Printing Industry:
2-HYDROXYETHYL ACETATE is used as a solvent in the printing industry for the preparation of inks and other printing materials. Its ability to dissolve a wide range of substances makes it suitable for use in various printing applications.
Used in Flavor and Fragrance Industry:
2-HYDROXYETHYL ACETATE is used as a solvent in the flavor and fragrance industry to dissolve and stabilize various aromatic compounds, enhancing the overall scent and flavor profiles of products.

Air & Water Reactions

Water soluble.

Reactivity Profile

2-HYDROXYETHYL ACETATE can react with oxidizing materials.

Fire Hazard

2-HYDROXYETHYL ACETATE is combustible.

Purification Methods

Dry the ester over K2CO3 (not CaCl2), and distil it. [Davis & Ross J Chem Soc 3061 1950, rate of hydrolysis: Davis & Ross J Chem Soc 2706 1951, Beilstein 2 H 141, 2 I 66, 2 II 154, 2 III 303, 2 IV 214.]

Check Digit Verification of cas no

The CAS Registry Mumber 542-59-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,4 and 2 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 542-59:
(5*5)+(4*4)+(3*2)+(2*5)+(1*9)=66
66 % 10 = 6
So 542-59-6 is a valid CAS Registry Number.
InChI:InChI=1/C4H8O3/c1-4(6)7-3-2-5/h5H,2-3H2,1H3

542-59-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Hydroxyethyl Acetate

1.2 Other means of identification

Product number -
Other names 1,2-Ethanediol, monoacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:542-59-6 SDS

542-59-6Relevant articles and documents

Evidence for the HOOO- anion in the ozonation of 1,3-dioxolanes: Hemiortho esters as the primary products

Plesnicar, Bozo,Cerkovnik, Janez,Tuttle, Tell,Kraka, Elfi,Cremer, Dieter

, p. 11260 - 11261 (2002)

Low-temperature ozonation (-78 °C) of 2-methyl-1,3-dioxolane (1a) in acetone-d6, methyl acetate, and tert-butyl methyl ether produced both the corresponding acetal hydrotrioxide (3a, ROOOH) and the hemiortho ester (2a, ROH) in molar ratio 1:5. Both intermediates were fully characterized by 1H, 13C, and 17O NMR spectroscopy, and they both decomposed to the corresponding hydroxy ester at higher temperatures. The mechanism involving the HOOO- anion formed by the abstraction of the hydride ion by ozone to form an ion pair, R+ -OOOH, with its subsequent collapse to either the corresponding hemiortho ester (ROH) or the acetal hydrotrioxide (ROOOH) was proposed. This mechanism is supported by the PISA/B3LYP/6-311++G(3df,3pd) calculations. Copyright

MECHANISM FOR FORMATION OF ETHYLENE GLYCOL MONOACETATE FROM ETHYLENE IN ACETIC ACID SOLUTION CONTAINING LITHIUM NITRATE AND PALLADIUM ACETATE

Kuznetsova, N. I.,Likholobov, V. A.,Fedotov, M. A.,Ermakov, Yu. I.

, p. 2475 - 2477 (1982)

-

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Luo, Jie,Rauch, Michael,Avram, Liat,Ben-David, Yehoshoa,Milstein, David

supporting information, p. 21628 - 21633 (2021/01/11)

Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.

THIAZOLIDINONE COMPOUNDS AND USE THEREOF

-

Paragraph 1284-1285, (2017/09/21)

A pharmaceutical composition containing a compound of Formula (I) for treating an opioid receptor-associated condition. Also disclosed is a method for treating an opioid receptor-associated condition using such a compound. Further disclosed are two sets of thiazolidinone compounds of formula (I): (i) compounds each having an enantiomeric excess greater than 90% and (ii) compounds each being substituted with deuterium.

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