54226-26-5Relevant articles and documents
Oxidations with Lead Tetraacetate. V. Oxidations of 1,3-Benzoxathioles
Aromdee, Chantana,Cole, Edward R.,Crank, George
, p. 1255 - 1261 (2007/10/02)
2,2-Disubstituted 1,3-benzoxathioles are easily oxidized by lead tetraacetate to a complex mixture of products.Acetoxylation takes place on the first carbon atom of the 2-alkyl or -cycloalkyl substituent giving acetoxy derivatives.The hetero ring is also opened yielding ketones, acetoxyketones, a disulfide and polymeric materials.Oxidation at the sulfur atom appears to be a minor reaction and no products oxidized in the benzene ring are found.