5424-25-9Relevant articles and documents
Synthesis, characterization, and molecular structures of di- and triorganotin(IV) complexes with 9-anthracenecarboxylic acid: The structural diversity in organotin 9-anthracenecarboxylates
Amini, Mostafa M.,Azadmeher, Amirreza,Khavasi, Hamid Reza,Ng
, p. 3922 - 3930 (2007)
The di- and triorganotin(IV) derivatives of anthracenecarboxylic acid, Ph2MeSnOC(O)C14H9 (2), Me3SnOC(O)C14H9 (3), Me2Sn[OC(O)C14H9]2 · CH3OH (4) Ph3SnOC(O)C14H9 · CH3OH (5), Ph2EtSnOC(O)C14H9 (6), Ph2Sn[OC(O)(C14H9)]2 (7) and PhMe2SnOC(O)C14H9 (8) were synthesized by the reaction of Ph2MeSnI, Me3SnCl, Me2SnCl2, Ph3SnCl, Ph2EtSnI, Ph2SnCl2, and PhMe2SnI with 9-anthracenecarboxylic acid, respectively, with the aid of potassium iso-propoxide. All complexes were characterized by elemental analysis, mass spectrometry, IR, 1H, 13C and 119Sn NMR spectroscopes. The molecular structures of complexes 2, 3 and 4 were determined by single crystal X-ray analysis. The X-ray structures reveal that complex 2 and 3 adopt a polymeric trans-C3SnO2 trigonal bipyamidal configuration with the oxygen atoms occupying axial positions. Complex 4 adopts a monomeric structure with two carboxylates coordinated to tin in a monodentate form from axial and equatorial positions, and with the coordination number raised to five as the methanol occupies the apical position of the trigonal bipyramid.
Reactions of organolanthanide compounds RLnI (Ln = Yb, Eu, Sm) with organic derivatives of silicon, tin, lead, and antimony
Rybakova,Syutkina,Petrov
, p. 244 - 246 (2007/10/03)
Reactions of compounds RLnI (R = Alk, Ar; Ln = Yb, Eu, Sm) with hexaalkyl(aryl)-distannanes, trimethylsilyltriphenyltin, and lead and antimony acetates were studied. The reactions with Sn-Sn and Si-Sn organic derivatives result in cleavage of Sn-Sn amd Sn-Si bonds with formation of tetrasubstituted stannanes and reactive organometallic derivatives with an Sn-Ln or Si-Ln bond. The reactions of RYbI with lead and antimony acetates and with tetraethoxysilane cause cleavage of the Pb-O, Sb-O, or Si-O bond with formation of tetrasubstituted derivatives of lead and silicon or trisubstituted antimony derivatives.