54245-99-7

Basic information

• Product Name: Benzamide, N-methoxy-N-phenyl-
• CAS NO: 54245-99-7
• Molecular Formula: C14H13NO2
• Molecular Weight: 227.263
• Mol File: 54245-99-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzamide, N-methoxy-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-methoxy-N-phenyl-(54245-99-7)
• EPA Substance Registry System: Benzamide, N-methoxy-N-phenyl-(54245-99-7)

Safety Data

• Hazardous Substances Data: 54245-99-7(Hazardous Substances Data)

Upstream product

• 304-88-1 N-phenylbenzohydroxamic acid 
• 77-78-1 dimethyl sulfate 
• 74-88-4 methyl iodide 
• 2446-51-7 N-methoxybenzamide 
• 58109-40-3 diphenyliodonium hexafluorophosphate 
• 71-43-2 benzene 
• 591-50-4 iodobenzene 
• 100-65-2 N-Phenylhydroxylamine 
• 98-88-4 benzoyl chloride 
• 32685-16-8 potassium benzohydroxamate 
• 112403-77-7 O-methyl N-chlorobenzohydroxamate 
• 186581-53-3 diazomethane 
• 110875-78-0 N-Phenyl-N-phenylacetoxy-benzamide 
• 134810-80-3 N-(3-Methyl-butyryloxy)-N-phenyl-benzamide 

Downstream Products

• 1015-89-0 6(5H)-phenanthridinone 
• 1227476-15-4 Azobenzene 
• 106-47-8 4-chloro-aniline 
• 65-85-0 benzoic acid 
• 304-88-1 N-phenylbenzohydroxamic acid 
• 5395-00-6 N-(2-methoxyphenyl)benzamide 

Relevant articles and documents

Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

Oxidative coupling strategies that can directly convert the C-H group for chemical transformations are, in theory, ideal synthetic methods to reduce the number of synthetic steps and byproduct generation. Hypervalent iodine reagents have now become one of the most promising tools in developing oxidative couplings due to their unique reactivities that are replacing metal oxidants. As part of our continuous development of oxidative coupling reactions, we describe in this report highly efficient μ-oxo hypervalent iodine catalysts for the direct oxidative coupling of N -methoxyamides and related compounds with aromatic hydrocarbons. The excellent TONs, up to over 100 times, with a best catalyst loading of 0.5 mol% were determined for the oxidative C-H/N-H coupling method, which can provide the most straightforward route to obtaining these unique arylamide compounds.

Cesium Carbonate Promoted Direct Arylation of Hydroxylamines and Oximes with Diaryliodonium Salts

A transition-metal-free approach for the arylation of hydroxylamines and oximes with diaryliodonium salts was developed. The reaction proceeded smoothly at room temperature in the presence of cesium carbonate. As a result, a wide range of N- and O-arylate

Copper-catalyzed cross-coupling of O -alkyl hydroxamates with aryl iodides

N-Aryl-O-alkylhydroxamic acid derivatives were prepared by copper-catalyzed cross-coupling of hydroxamates with aryl iodides. The reaction conditions are compatible with standard hydroxy-protecting groups on the hydroxylamine moiety and are applicable to