54411-93-7Relevant articles and documents
Homogeneous catalytic dehalodimerization of 17-iodo-Δ16 steroids
Skoda-Foeldes, Rita,Csakai, Zita,Kollar, Laszlo,Szalontai, Gabor,Horvath, Judit,Tuba, Zoltan
, p. 786 - 790 (1995)
17-Iodo-Δ16 steroids undergo selective dimerization and carbonylative dimerization in the presence of palladium catalysts in dimethylformamide which result in 16-17'-coupled dienes and 17-carboxylic anhydrides, respectively.Moderate to good yields have been obtained for both types of dimers. - Keywords: dehalodimerization of steroids; steroidal anhydrides; conjugated dimeric dienes; homogeneous palladium(0) catalysts