54458-32-1

Basic information

• Product Name: 1-(4-chlorophenyl)-3-phenylpropane-1,2,3-trione
• Synonyms: 1-(4-chlorophenyl)-3-phenylpropane-1,2,3-trione
• CAS NO: 54458-32-1
• Molecular Weight: 272.688
• Mol File: 54458-32-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(4-chlorophenyl)-3-phenylpropane-1,2,3-trione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-chlorophenyl)-3-phenylpropane-1,2,3-trione(54458-32-1)
• EPA Substance Registry System: 1-(4-chlorophenyl)-3-phenylpropane-1,2,3-trione(54458-32-1)

Safety Data

• Hazardous Substances Data: 54458-32-1(Hazardous Substances Data)

Upstream product

• 6969-01-3 phenyl-3-(4-chlorophenyl)oxiran-2-ylmethanone 
• 32157-73-6 1-(p-chlorophenyl)-2,3-epoxy-3-phenylpropan-1-one 
• 956-02-5 4'-chlorochalcone 
• 25856-06-8 2,3-dibromo-1-(4-chloro-phenyl)-3-phenyl-propan-1-one 
• 5633-34-1 (benzoylmethylene)dimethylsulfurane 
• 14189-18-5 4-Chlor-benzoesaeure-kohlensaeure-ethylester-anhydrid 
• 26031-66-3 1-(4-Chlorphenacyl)pyridiniumbromid 
• 98-88-4 benzoyl chloride 
• 17055-50-4 Pyridinium-(benzoyl)(4-chlorbenzoyl)methanid 
• 25352-03-8 1-(4-chlorophenyl)-2-diazo-3-phenylpropane-1,3-dione 
• 54458-29-6 2-bromo-1-(4-chlorophenyl)-3-phenyl-1,3-propanedione 
• 17059-59-5 1-(4-chloro-phenyl)-3-phenyl-propane-1,3-dione 

Relevant articles and documents

LiBr/β-CD/IBX/H2O-DMSO: A new approach for one-pot biomimetic regioselective ring opening of chalcone epoxides to bromohydrins and conversion to 1,2,3-triketones

Highly regioselective ring cleavage of chalcone epoxides to bromohydrins has been carried out in good yields with LiBr in the presence of β-CD using DMSO-H2O as solvent system. The ring-opened product, i.e., bromohydrin, was well adapted to IBX-mediated oxidation in such a fashion that the bromohydrins are transformed to their corresponding 1,2,3-triketones in moderate-to-good yields in one pot.

Introduction of Oxygen Functions into the α-Position of β-Diketones, 8. Ozonolysis of Sulfonium Ylides

(Dimethylsulfonio)diacylmethanides 1, prepared by known methods, are cleaved by equimolar amounts of ozone in aprotic medium yielding vicinal triketones 2 and DMSO.Peroxydic reaction products are not detectable.