54492-85-2Relevant articles and documents
Preparation of Conjugated Carbonyl Compounds by Photolysis of η3-Allylpalladium Complexes
Muzart, Jacques,Pale, Patrick,Pete, Jean-Pierre
, p. 668 - 669 (1981)
Irradiation at 366 nm of oxygenated solutions of η3-allylpalladium complexes leads to unsaturated carbonyl compounds.
INDUCTION PAR LA LUMIERE DE L'OXYDATION DES COMPLEXES Η3-ALLYLPALLADIUM PAR L'OXYGENE MOLECULAIRE
Muzart, J.,Pale, P.,Pete, J.P.,Riahi, A.
, p. 731 - 739 (2007/10/02)
Irradiation at λ=366 nm of oxygenated solutions of η3-allylpalladium complexes leads to unsaturated carbonyl compounds.Substitution of the η3-allyl ligand by an electron withdrawing group could induce a regioselective oxidation of the allylic position farthest from this group.The efficiency of these reactions is sensible to the nature of the solvent.