54502-24-8

Basic information

• Product Name: Copper, 1-octynyl-
• CAS NO: 54502-24-8
• Molecular Formula: C8H13Cu
• Molecular Weight: 172.737
• Mol File: 54502-24-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Copper, 1-octynyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Copper, 1-octynyl-(54502-24-8)
• EPA Substance Registry System: Copper, 1-octynyl-(54502-24-8)

Safety Data

• Hazardous Substances Data: 54502-24-8(Hazardous Substances Data)

Upstream product

• 129083-29-0 Pentadec-8-yn-7-ol 

Downstream Products

• 888329-96-2 3-(oct-1-yn-1-yl)oxazolidin-2-one 
• 1352009-98-3 N-(diphenylmethylene)-oct-1-yn-1-amine 
• 1451265-22-7 dicyclohexyl(oct-1-yn-1-yl)phosphine-borane 
• 1019944-15-0 diisopropyl (oct-1-yn-1-yl)phosphonate 
• 3450-66-6 diethyl (oct-1-yn-1-yl)phosphonate 
• 18277-20-8 hexadeca-7,9-diyne 
• 172221-61-3 (oct-1-yn-1-yl)diphenylphosphine oxide 
• 1207551-89-0 2-(oct-1-yn-1-yl)-5-phenyl-1,3,4-oxadiazole 
• 1388044-76-5 (Z)-N-[1-(2,3-dimethylphenyl)pentylidene]pent-1-yn-1-amine 
• 1388044-79-8 (E)-N-[1-(2,3-dimethylphenyl)pentylidene]pent-1-yn-1-amine 
• 1388045-07-5 N-[1-(2-chlorophenyl)pentylidene]pent-1-yn-1-amin 
• 1388045-08-6 C₁₆H₂₀ClN 
• 1451265-18-1 cyclohexylmethyl(oct-1-yn-1-yl)phosphine-borane 
• 1388045-29-1 (Z)-N-[1-(2-methoxyphenyl)propylidene]oct-1-yn-1-amine 

Relevant articles and documents

SELECTIVE REDUCTION OF ALKYNES TO CIS-ALKENES BY HYDROMETALLATION USING 6

Selective reduction of alkynes to the corresponding alkenes is reported using the stable, readily prepared copper(I) hydride reagent, 6.Terminal alkynes are reduced at room temperature, unactivated internal alkynes react only at elevated temperature.Disubstituted alkynes with propargyl activation are also reduced, giving cis-olefins selectively.Protection of propargylic alcohol functionality is unnecessary, although fragmentation is sometimes competitive in sterically hindered cases.A tertiary propargyl acetate gave displacement to the allene exclusively.