54595-10-7

Basic information

• Product Name: (1R,5R,8S,10Z)-(-)-8-(2-Pentenyl)-2-oxabicyclo<3.2.1>octan-3-on
• Synonyms: (1R,5R,8S,10Z)-(-)-8-(2-Pentenyl)-2-oxabicyclo<3.2.1>octan-3-on
• CAS NO: 54595-10-7
• Molecular Weight: 194.274
• Mol File: 54595-10-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (1R,5R,8S,10Z)-(-)-8-(2-Pentenyl)-2-oxabicyclo<3.2.1>octan-3-on(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,5R,8S,10Z)-(-)-8-(2-Pentenyl)-2-oxabicyclo<3.2.1>octan-3-on(54595-10-7)
• EPA Substance Registry System: (1R,5R,8S,10Z)-(-)-8-(2-Pentenyl)-2-oxabicyclo<3.2.1>octan-3-on(54595-10-7)

Safety Data

• Hazardous Substances Data: 54595-10-7(Hazardous Substances Data)

Upstream product

• 16666-78-7 propylidenetriphenylphosphorane 
• 807355-33-5 (1R,5S,6R)-6-methoxycarbonylmethyl-3-hydroxy-2-oxabicyclo<3.3.0>octane 
• 128777-71-9 ((1R,5R,8S)-3-Oxo-2-oxa-bicyclo[3.2.1]oct-8-yl)-acetaldehyde 
• 126783-82-2 (1R,2S,3R,2''Z)-3-Hydroxy-1-(2-hydroxyethyl)-2-(2-pentenyl)cyclopentan 
• 95722-42-2 (+)-7-iso-jasmonic acid methyl ester 
• 126664-42-4 (1R,2R,3R)-3-(Benzyloxy)-1-(2-hydroxyethyl)-2-(2-methoxyethenyl)cyclopentan 
• 53320-18-6 ((3aR,4S,6aS)-2-Hydroxy-hexahydro-cyclopenta[b]furan-4-yl)-acetic acid methyl ester 
• 34638-25-0 (1R,5S)-2-oxabicyclo[3.3.0]oct-6-en-3-one 
• 807355-29-9 4-((benzenesulfonyl)methyl)-2-methoxy-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan 
• 807355-27-7 4-((phenylsulfanyl)methyl)-3,3a,4,6a-tetrahydro-cyclopenta[b]furan-2-one 
• 6228-47-3 n-propyltriphenylphosphonium bromide 
• 118285-12-4 dimethyl 2-(2,2-dimethoxyethyl)-2-cyclopentenylmalonate 
• 118285-13-5 methyl 2-(2,2-dimethoxyethyl)-2-cyclopentenylacetate 
• 118285-11-3 2-(2,2-dimethoxyethyl)-2-cyclopentenylacetate 

Downstream Products

• 1211-29-6 methyl (2-(2-pent-2Z-enyl)-3-oxocyclopentyl)acetate 
• 34027-33-3 (+/-)-Cucurbic acid 
• 1211-29-6 Methyl jasmonate 
• 34027-33-3 [(1S,2R,3S)-3-Hydroxy-2-((Z)-pent-2-enyl)-cyclopentyl]-acetic acid 

Relevant articles and documents

A general enantioselective approach to jasmonoid fragrances: Synthesis of (+)-(1R,2S)-methyl dihydrojasmonate and (+)-(1R,2S)-magnolione

Methyl dihydrojasmonate 1 and magnolione 3 are of both academic and industrial interest. In this paper, we describe a flexible, high-yielding route to diastereomerically pure (+)-cis-(1R,2S)-methyl dihydrojasmonate 1 and the first synthesis of (+)-cis-(1R

Synthesis of Chiral Methyl Cucurbate and Its Analogs

Natural (+)-(1R,2S,3S)-methyl cucurbate (1b) and the (-)-δ-lactone of 3-epi-cucurbic acid (16) were synthesized from (+)-(1R,6S,7R)-bicyclonon-3-en-7-ol (5).Asymmetric hydrolysis of the acetate (8) of (+/-)-5 with pancreatin gave optically pure the

Chemistry and Stereochemistry of Iridoids, XIII. - Synthesis of Enantiomerically Pure Methyl (1R,2S,2''Z)-(+)-Jasmonate Starting from Catalpol

Enantiomerically pure methyl (1R,2S,2''Z)(+)-jasmonate (2), which was recognized as a component of the fragrance of the jasmine flower oil, was synthesized starting from catalpol (3). 2 is easily epimerized to 1.Thus, it is necessary to use very mild conditions in the course of the synthesis and purification.These results raise the question whether 2 exists as a natural product in the flower of jasmine and 1 arises during the isolation.