54623-22-2

Basic information

• Product Name: methyl 2,3,6-trideoxy-3-triaza-1,2-dien-2-ium-1-ylhexopyranoside
• CAS NO: 54623-22-2
• Molecular Formula: C₇H₁₃N₃O₃
• Molecular Weight: 188.2038
• Mol File: 54623-22-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl 2,3,6-trideoxy-3-triaza-1,2-dien-2-ium-1-ylhexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,6-trideoxy-3-triaza-1,2-dien-2-ium-1-ylhexopyranoside(54623-22-2)
• EPA Substance Registry System: methyl 2,3,6-trideoxy-3-triaza-1,2-dien-2-ium-1-ylhexopyranoside(54623-22-2)

Safety Data

• Hazardous Substances Data: 54623-22-2(Hazardous Substances Data)

Upstream product

• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 96796-65-5 methyl 2,6-dideoxy-3-O-methanesulphonyl-4-O-methoxymethyl-α-L-ribo-hexopyranoside 
• 96796-64-4 methyl 2,6-dideoxy-4-O-methoxymethyl-α-L-ribo-hexopyranoside 
• 87858-14-8 3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hex-1-enitol 
• 114412-85-0 4-O-Acetyl-2,3,6-trideoxy-L-erythro-hex-2-enopyranose 
• 114412-96-3 methyl 4-O-acetyl-3-azido-2,3,6-trideoxy-α-L-arabino-hexopyranoside 
• 96796-66-6 methyl 3-azido-2,3,6-trideoxy-4-O-methoxymethyl-α-L-arabino-hexopyranoside 
• 67909-18-6 Methyl 3,4-anhydro-2,6-dideoxy-α-L-ribo-hexopyranoside 
• 67-56-1 methanol 
• 20770-58-5 Acetic acid (1S,2S)-2,3-diacetoxy-1-((S)-1,2-diacetoxy-ethyl)-4-nitro-butyl ester 
• 87782-52-3 Methyl 2-deoxy-α-L-arabino-hexopyranoside 6-p-toluenesulfonate 
• 87858-15-9 3,4,5,6-Tetra-O-acetyl-1,2-dideoxy-1-nitro-L-arabino-hexitol 
• 87782-54-5 Methyl 2,6-dideoxy-6-iodo-α-L-arabino-hexopyranoside 
• 18981-61-8 Methyl 2,6-dideoxy-α-L-arabino-hexopyranoside 3-p-toluenesulfonate 

Downstream Products

• 18977-92-9 methyl α-L-daunosaminide 
• 18981-64-1 Methyl 3-azido-2,3,6-trideoxy-α-L-lyxo-hexopyranoside 
• 103082-86-6 phenyl 2-O-(3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-β-L-arabino-hexopyranosyl)-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 103082-85-5 phenyl 2-O-(3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranosyl)-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 103082-87-7 phenyl 2-O-(3-azido-2,3,6-trideoxy-α-L-arabino-hexopyranosyl)-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 149055-63-0 3-Azido-1,4-di-O-(p-nitrobenzoyl)-2,3,6-trideoxy-α,β-L-arabino-hexopyranose 
• 130321-47-0 4-Nitro-benzoic acid (2S,3R,4S)-4-azido-6-chloro-2-methyl-tetrahydro-pyran-3-yl ester 
• 103082-90-2 phenyl β-acobioside 
• 18981-62-9 methyl 3-azido-2,3,6-trideoxy-4-O-methanesulphonyl-α-L-arabino-hexopyranoside 
• 103082-83-3 methyl 3-azido-2,3,6-trideoxy-4-O-p-nitrobenzoyl-α-L-arabino-hexopyranoside 
• 54623-23-3 methyl-3-amino-2,3,6-tridesoxy-α-L-arabino-hexopyranoside 

Relevant articles and documents

C-glycosylation of oxygenated naphthols with 3-dimethylamino- 2,3,6-trideoxy-L-arabino-hexopyranose and 3-azido- 2,3,6-trideoxy-D-arabino-hexopyranose

In connection with studies directed towards the synthesis of the pyranonaphthoquinone antibiotic medermycin, C-aryl glycosides were prepared by C-glycosylation of naphthols with glycosyl donors. Boron trifluoride diethyl etherate proved to be a suitable Lewis acid to promote the C-glycosylation, and use of the azido glycosyl donor proved more successful than using the dimethylamino glycosyl donor. 5-Hydroxy-1,4-dimethoxynaphthalene underwent facile C-glycosylation with two particular glycosyl donors, whereas 3-bromo-5-hydroxy-1,4-dimethoxynaphthalene was not an effective coupling partner with the same glycosyl donors. These studies indicate that subtle steric and electronic effects need to be considered in order to fine-tune C-glycosylations when using highly functionalized glycosyl donors.

Addition of Hydrazoique Acid to Pseudoglycals Stereoselective Synthesis of L-Acosamine and L-Daunosamine

Methyl and benzyl glycosides and glycal of L-acosamine (3-amino-2,3,6 trideoxy-L-arabino-hexose) have been stereoselectively prepared via 1,4-addition of hydrazoic acid to L-erythro-hex-2-enopyranose as a key step.Inversion of the C-4 configuration of met

CONVENIENT SYNTHESYS OF L-DAUNOSAMINE AND L-ACOSAMINE

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