54655-43-5

Basic information

• Product Name: Cyclohexanol, 1-(2-butenyl)-
• CAS NO: 54655-43-5
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 54655-43-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-(2-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-(2-butenyl)-(54655-43-5)
• EPA Substance Registry System: Cyclohexanol, 1-(2-butenyl)-(54655-43-5)

Safety Data

• Hazardous Substances Data: 54655-43-5(Hazardous Substances Data)

Upstream product

• 7204-29-7 trans-2-butenyl acetate 
• 108-94-1 cyclohexanone 
• 4784-77-4 (E/Z)-crotyl bromide 
• 628-08-0 crotyl acetate 
• 6737-11-7 2-acetoxy-3-butene 

Relevant articles and documents

Ni-catalyzed activation of α-chloroesters: a simple method for the synthesis of α-arylesters and β-hydroxyesters

Coupling reactions of α-chloroesters with aryl halides (α-arylation) or carbonyl compounds (Reformatsky) using nickel catalyst allow, under mild conditions, the preparation of various functionalized aryl propionic acid derivatives or β-hydroxyesters. In the synthesis of aryl propionic acid derivatives, the process is efficient with aryl halides bearing either electron-withdrawing or electron-donating groups.

Iron-catalyzed electrochemical allylation of carbonyl compounds by allylic acetates

Homoallylic alcohols were synthesized from aldehydes or ketones and allylic acetates, using an electrochemical process catalyzed by iron complexes. We first studied the reactivity of allyl acetate, using N,N-dimethylformamide (DMF) or acetonitrile (AN) as solvent, FeBr2 as catalyst, and Fe as the sacrificial anode. Then we tested the regioreactivity of crotyl acetate and other allylic derivatives.

REDUCTIVE COUPLING OF ALLYLIC ACETATES WITH CARBONYL COMPOUNDS BY USING Pd(O)-SmI2 SYSTEM

Reductive coupling of allylic acetates with carbonyl compounds proceeded by SmI2 in the presence of catalytic Pd(O) to yield homoallylic alcohols.