54698-17-8Relevant articles and documents
Stereoselective synthesis of Heliannuol G
Sarkar, Debayan,Ghosh, Manoj Kumar
, p. 4336 - 4339 (2017/10/18)
The first stereoselective synthesis of Heliannuol G has been achieved employing an o-quinone methide intermediate. The present synthesis triumphs over all the drawbacks associated with the reported one and reveals an impressive overall yield of 12.37%.
Biomimetic Total Synthesis of Paeoveitol
Zhang, Yuhan,Guo, Yonghong,Li, Zhongle,Xie, Zhixiang
, p. 4578 - 4581 (2016/09/28)
A highly stereocontrolled synthesis of paeoveitol has been developed in 26% yield, in 7 steps from commercially available materials. The synthetic strategy was inspired primarily by the biogenetic hypothesis and was enabled by hetero-Diels-Alder cycloaddi
Synthesis of heliannane skeletons. Facile preparation of (±)-heliannuol D
Macías, Francisco A.,Chinchilla, David,Molinillo, José M. G.,Marín, David,Varela, Rosa M.,Torres, Ascensión
, p. 1679 - 1683 (2007/10/03)
Heliannuol D is a natural product with a 7,10-heliannane skeleton, isolated from Helianthus annuus. It has been synthesized in eight steps, in good yield, using a new biomimetic method. Key steps were a Fries rearrangement, a Grignard reaction and, finall