54731-56-5

Basic information

• Product Name: Silane, cyclohexylmethoxydimethyl-
• CAS NO: 54731-56-5
• Molecular Formula: C9H20OSi
• Molecular Weight: 172.343
• Mol File: 54731-56-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, cyclohexylmethoxydimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, cyclohexylmethoxydimethyl-(54731-56-5)
• EPA Substance Registry System: Silane, cyclohexylmethoxydimethyl-(54731-56-5)

Safety Data

• Hazardous Substances Data: 54731-56-5(Hazardous Substances Data)

Upstream product

• 71864-47-6 chloro-cyclohexyl-dimethylsilane 
• 10151-74-3 cyclohexyl-trimethyl-silane 
• 67-56-1 methanol 
• 931-51-1 cyclohexylmagnesiumchloride 
• 75-78-5 dimethylsilicon dichloride 
• 108-85-0 1-bromocyclohexane 
• 1825-68-9 dimethylmethoxychlorosilane 

Downstream Products

• 108-93-0 cyclohexanol 
• 71864-47-6 chloro-cyclohexyl-dimethylsilane 

Relevant articles and documents

Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)-H Borylation at the Methyl Group on Silicon

A conversion of trimethylsilylalkanes into the corresponding alcohols is established based on an iridium-catalyzed, chemoselective C(sp3)-H borylation of the methyl group on silicon. The (borylmethyl)silyl group formed by C(sp3)-H borylation is treated with H2O2/NaOH, and the resulting (hydroxymethyl)silyl group is converted into a hydroxyl group by Brook rearrangement, followed by oxidation of the resulting methoxysilyl group under Tamao conditions. An alternative route proceeding through the formylsilyl group formed from a (hydroxymethyl)silyl group by Swern oxidation is also established. The method is applicable to substituted trimethylsilylcycloalkanes and 1,1-dimethyl-1-silacyclopentane for conversion into the corresponding stereodefined cycloalkyl alcohols and 1,4-butanediol.

CHEMICAL ACTIVITY AND STERIC ACCESSIBILITY. XVIII. REACTION OF ALKOXYCHLOROSILANES WITH ORGANOMAGNESIUM COMPOUNDS

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