54985-63-6

Basic information

• Product Name: N-(Benzyl)imidodithiokohlensaeure-S,S'-dimethylester
• Synonyms: N-(Benzyl)imidodithiokohlensaeure-S,S'-dimethylester
• CAS NO: 54985-63-6
• Molecular Weight: 211.352
• Mol File: 54985-63-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: N-(Benzyl)imidodithiokohlensaeure-S,S'-dimethylester(CAS DataBase Reference)
• NIST Chemistry Reference: N-(Benzyl)imidodithiokohlensaeure-S,S'-dimethylester(54985-63-6)
• EPA Substance Registry System: N-(Benzyl)imidodithiokohlensaeure-S,S'-dimethylester(54985-63-6)

Safety Data

• Hazardous Substances Data: 54985-63-6(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 1643-19-2 tetrabutylammomium bromide 
• 74-88-4 methyl iodide 
• 75-15-0 carbon disulfide 

Downstream Products

• 55012-66-3 N-Benzylidenamin 
• 342896-10-0 N-(Benzyl)imidodithiokohlensaeure-S-methyl-S'-(trimethylsilyl)-methylester 
• 76697-96-6 N-<(Phenyl)(trimethylsilyl)methyl>imidodithiokohlensaeure-S,S'-dimethylester 
• 137628-94-5 1-Benzyl-3-methoxy-3-methyl-4,4-bis(methylthio)-2-azetidinone 
• 137628-95-6 1-Benzyl-3-(N,N-dibenzylamino)-4,4-bis(methylthio)-2-azetidinone 
• 1294450-07-9 1-(benzyl)-3-acetoxy-4,4-bis(methylthio)azetidin-2-one 
• 119493-02-6 N-Benzyl-2-phenoxy-malonamic acid methyl ester 
• 119492-98-7 1-Benzyl-3-phenoxy-azetidin-2-one 
• 142389-05-7 1-Benzyl-3-phenoxy-azetidine-2,4-dione 
• 137629-02-8 1-(Benzyloxy)-3-methoxy-3-methylazetidine-2,4-dione 
• 119492-92-1 1-benzyl-4,4-bis-methylsulfanyl-3-phenoxyazetidin-2-one 
• 5817-70-9 methyl N-benzylcarbamate 
• 76697-97-7 (+/-)-N-α-methylbenzyl carbonimidodithioic acid dimethyl ester 

Relevant articles and documents

4,4-Bis(methylthio)azetidin-2-ones as synthons of 1,2- and 1,3-dicarbonyl systems

The importance of β-lactams as synthetic building blocks has been widely recognized in organic synthesis due to possible ring cleavage at any of the four single bonds of the β-lactam ring. We now report reactions involving breaking of the N1-C4 bond in differently substituted at C3 4,4-bis(methylthio)azetidin-2-ones, leading to formation of 1,2- and 1,3-dicarbonyl systems.

Unique zeolite-catalyzed synthesis of nitroketene S,N-acetals

Dimethyl carbonimidodithioates (4a-g, 7a-c) derived from various primary amines and amino acid esters [glycine, (L)-alanine and (L)-phenylalanine] have been condensed with nitromethane in the presence of the rare-earth exchanged zeolite RE(70%)Na Y to give the S,N-acetals (5a-g, 8a-c). Mercuric chloride catalyzed hydrolysis of these (8a-c) has led to the nitroacetyl derivatives (9a-c). The glycine derivative (7a) gives a dimeric product (11) when heated alone with the zeolite.

Improved process for the preparation of 1-substituted amino-1-substituted thio-2-nitro alkenes

A process is disclosed for the manufacture of 1-substituted amino-1-substituted thio-2 nitro alkenes of the general formula: (R1NH) (R2S) C=CR3 (NO2) wherein R1, R2, R3, may be same or different and may consist of hydrogen, alkyl, aryl or arylalkyl groups