55233-98-2

Basic information

• Product Name: ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate
• Synonyms: ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate
• CAS NO: 55233-98-2
• Molecular Weight: 198.262
• Mol File: 55233-98-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate(55233-98-2)
• EPA Substance Registry System: ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate(55233-98-2)

Safety Data

• Hazardous Substances Data: 55233-98-2(Hazardous Substances Data)

Upstream product

• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 95-92-1 oxalic acid diethyl ester 
• 583-60-8 2-Methylcyclohexanone 
• 870-63-3 prenyl bromide 
• 105-56-6 ethyl 2-cyanoacetate 
• 201230-82-2 carbon monoxide 
• 66248-79-1 ethyl 4,4-dimethyl-3-oxo-hex-5-enoate 
• 74-88-4 methyl iodide 

Downstream Products

• 7507-68-8 1,3,3-trimethyl-2-oxocyclohexanecarboxylic acid ethyl ester 
• 94092-65-6 6,6-Dimethyl-2-(3-oxo-butyl)-2-ethoxycarbonyl-cyclohexanon-⁽¹⁾ 
• 92383-42-1 6-amino-2,2-dimethyl-cyclohexanone 
• 13487-68-8 2-Hydroxy-1,2,3,3-tetramethyl-cyclohexanecarboxylic acid 
• 90642-15-2 2,2-Dimethyl-6-oximino-cyclohexanon 

Relevant articles and documents

Sequential hydroformylation/aldol reactions: Versatile and controllable access to functionalised carbocycles from unsaturated carbonyl compounds

Three different modes of hydroformylation/aldol reaction sequences involving either acid-catalysed aldol reactions, Mukaiyama aldol addition of pre-formed enolsilanes or aldol addition of in situ generated boron enolates can be applied to unsaturated ketones and ketoesters to afford the corresponding carbocyclic aldol adducts in good yields proceeding through the intermediate activated ketoaldehydes. In selected cases, complimentary, synthetically useful diastereoselectivities were observed in the products.