55534-76-4

Basic information

• Product Name: dibenzyl (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-3,16-dioxo-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-12,25-dicarboxylate
• Synonyms: dibenzyl (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-3,16-dioxo-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-12,25-dicarboxylate
• CAS NO: 55534-76-4
• Molecular Weight: 746.985
• Mol File: 55534-76-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dibenzyl (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-3,16-dioxo-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-12,25-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzyl (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-3,16-dioxo-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-12,25-dicarboxylate(55534-76-4)
• EPA Substance Registry System: dibenzyl (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-3,16-dioxo-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-12,25-dicarboxylate(55534-76-4)

Safety Data

• Hazardous Substances Data: 55534-76-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 3463-92-1 (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-3,16-dione 
• 55438-00-1 8-{(2S,5S,6S)-1-[(benzyloxy)carbonyl]-5-hydroxy-6-methylpiperidinyl}octanoic acid 

Downstream Products

• 3463-92-1 (1S,11R,13S,14S,24R,26S)-13,26-dimethyl-2,15-dioxa-12,25-diazatricyclo[22.2.2.2^11,14]triacontane-3,16-dione 

Relevant articles and documents

Enantioselective Total Synthesis of (+)-Azimine and (+)-Carpaine

(Matrix presented) The enantioselective total syntheses of (+)-azimine and (+)-carpaine have been developed, starting with (S)-1,2,4-butanetriol as a single source of chirality. The key common feature in these syntheses involves stereoselective intramolecular hetero-Diels-Alder reaction of an acylnitroso compound. The critical macrocyclic dilactonization of the N-Cbz derivatives of azimic acid and carpamic acid was efficiently achieved by using the Yamguchi macrocyclization conditions.