55632-07-0Relevant articles and documents
REACTIONS OF TRIFLUOROMETHYL AND TRIPLET METHYLENE RADICALS WITH SOME ALKYLSILANES
Bell, T. N.,Marciniak, B.,Sherwood, A. G.
, p. 3818 - 3820 (1988)
The recombination of CF3 and CH2SiF3 radicals was used to prepare CF3CH2SiF3 by collisional stabilization of the initially formed hot molecule, CF3CH2SiF3*.One fate of this hot species, not so far observed, is its decomposition to give CF3CH2 and SiF3 radicals, a process which leads to additional products.In separate studies of the reactions of 3CH2 with CF3CH2SiF3, the formation of CH3SiF3 is observed, and this is suggested to be through a 5-coordinate radical exchange process.
