556776-86-4Relevant articles and documents
Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: Efficient and general trans addition
Trost, Barry M.,Ball, Zachary T.
, p. 17644 - 17655 (2007/10/03)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes, Terminal alkynes afford access to α-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans
Ruthenium-catalyzed vinylsilane synthesis and cross-coupling as a selective approach to alkenes: benzyldimethylsilyl as a robust vinylmetal functionality.
Trost, Barry M,Machacek, Michelle R,Ball, Zachary T
, p. 1895 - 1898 (2007/10/03)
[reaction: see text] Ruthenium-catalyzed alkyne hydrosilylation or silyl-alkyne Alder ene reactions provide entry into benzyldimethylsilyl (BDMS)-substituted alkenes. The BDMS-vinylsilanes are further elaborated through mild palladium-catalyzed cross coup
