55915-75-8Relevant articles and documents
Bismuth (III) salts as catalysts in the opening of epoxides by amines
Oussaid, Adyl,Garrigues, Bernard,Oussaid, Boualem,Benyaquad, Fatima
, p. 2315 - 2320 (2002)
BiCl3 and Bi (OTf)3 catalyze the opening of epoxides (1-7) by amines (8-12). High regioselectivities are observed. BiCl3 et Bi (OTf)3 catalysent la reaction d'ouverture des epoxydes (1-7) par les amines (8-12). La reaction est fortement regioselective.
Preparation of Vicinal N-Alkylamino Alcohols via Acylation-Rearrangement of Nitrones Followed by Hydride Reduction
Coates, Robert M.,Cummins, Clark H.
, p. 1383 - 1389 (2007/10/02)
Acylation-rearrangement of N-tert-butyl and N-cyclohexyl nitrones of cyclohexanecarboxaldehyde (1), n-butyraldehyde, isobutyraldehyde, 3-cyclohexenecarboxaldehyde, and α-methylpropionaldehyde gave α-pivaloyloxy imines, which underwent reduction with lithi