560132-06-1

Basic information

• Product Name: (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane
• Synonyms: (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane
• CAS NO: 560132-06-1
• Molecular Weight: 222.79
• Mol File: 560132-06-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane(560132-06-1)
• EPA Substance Registry System: (E)-(buta-1,3-dien-1-yl)(chloromethyl)methyl(phenyl)silane(560132-06-1)

Safety Data

• Hazardous Substances Data: 560132-06-1(Hazardous Substances Data)

Upstream product

• 627-22-5 1-chloroprene 
• 2632-83-9 chloro(chloromethyl)methyl(phenyl)silane 

Downstream Products

• 560132-12-9 (E)-2-methyl-2-phenyl-2-silahexa-3,5-dien-1-yl acrylate 
• 560132-09-4 (E)-2-methyl-2-phenyl-2-silahexa-3,5-dien-1-ol 

Relevant articles and documents

Highly diastereoselective intramolecular Diels-Alder reaction of chiral silatrienes

New Si-chiral 2-silahexa-3,5-dienyl acrylates were prepared in six steps from dichloro(chloromethyl)methylsilane. The EtAlCl2 catalysed intramolecular Diels-Alder reaction of these compounds gave chiral 4-sila-4a,7,8,8a-tetrahydroisochroman-1-ones in good yield. Very good diastereoselectivity was observed for a silatriene bearing a methyl and a 2-methoxyphenyl substituent on the chiral silicon atom.