56029-18-6

Basic information

• Product Name: (2E)-2-amino-3-{[(E)-phenylmethylidene]amino}but-2-enedinitrile
• Synonyms: 2-amino-3-(benzylideneamino)-2-butenedinitrile; 2-amino-3-(benzylideneamino)but-2-enedinitrile
• CAS NO: 56029-18-6
• Molecular Formula: C₁₁H₈N₄
• Molecular Weight: 196.208
• Mol File: 56029-18-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 395.2°C at 760 mmHg
• Flash Point: 192.8°C
• Density: 1.11g/cm³
• Vapor Pressure: 1.87E-06mmHg at 25°C
• Refractive Index: 1.59
• CAS DataBase Reference: (2E)-2-amino-3-{[(E)-phenylmethylidene]amino}but-2-enedinitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-2-amino-3-{[(E)-phenylmethylidene]amino}but-2-enedinitrile(56029-18-6)
• EPA Substance Registry System: (2E)-2-amino-3-{[(E)-phenylmethylidene]amino}but-2-enedinitrile(56029-18-6)

Safety Data

• Hazardous Substances Data: 56029-18-6(Hazardous Substances Data)

Usage

Description

(2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile is a dienitrile derivative with the molecular formula C11H13N5. It features a but-2-enedinitrile backbone, with an amino group attached to the second carbon and a substituted phenylmethylideneamino group on the third carbon. (2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile belongs to the class of organic compounds known as nitriles.

Uses

Used in Medicinal Chemistry:
(2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile is used as a potential candidate in medicinal chemistry due to its unique structure and properties. Its ability to form hydrogen bonds and coordinate with metal ions may contribute to its potential use in the development of new pharmaceuticals.
Used in Organic Synthesis:
As a dienitrile derivative, (2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile can be used as an intermediate in organic synthesis for the preparation of various organic compounds. Its reactivity and functional groups make it a versatile building block for the synthesis of complex molecules.
Used in Materials Science:
(2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile may also find applications in materials science, where its unique structure could be utilized to develop new materials with specific properties. Further research is needed to explore its potential in this field.
Further research and investigation are required to fully understand the potential uses and properties of (2E)-2-amino-3-[(E)-phenylmethylidene]aminobut-2-enedinitrile. Its unique structure and properties suggest that it may have a wide range of applications across different industries.

Upstream product

• 28321-79-1 diiminosuccinonitrile 
• 544-25-2 Cyclohepta-1,3,5-triene 
• 127896-76-8 N-(1-chlorobenzyl)pyridinium chloride 
• 1187-42-4 diaminomaleonitrile 
• 127896-78-0 N-(1-chlorobenzyl)pyrimidinium chloride 
• 108-88-3 toluene 
• 18514-52-8 2,3-diaminomaleonitrile 
• 100-52-7 benzaldehyde 

Downstream Products

• 68568-17-2 2-Amino-3-(benzylidenamino)-3-cyanoacrylamid 
• 51802-03-0 N-Benzyldiaminomaleonitrile 
• 51802-51-8 N,N-Dibenzyldiiminosuccinonitril 
• 51802-24-5 (Z)-2-Benzylamino-3-{[1-phenyl-meth-(E)-ylidene]-amino}-but-2-enedinitrile 
• 51802-04-1 N,N'-dibenzyldiaminomaleonitrile 
• 888-60-8 2-phenyl-1H-imidazole-4,5-dicarboxylic acid 
• 50847-06-8 2-Phenyl-4,5-dicyanoimidazole 
• 66371-28-6 (Z)-3-Cyano-3-{[1-phenyl-meth-(Z)-ylidene]-amino}-2-{[1-p-tolyl-meth-(Z)-ylidene]-amino}-acrylamide 

Relevant articles and documents

Spectroscopic studies of the intramolecular hydrogen bonding in o-hydroxy Schiff bases, derived from diaminomaleonitrile, and their deprotonation reaction products

The structural study of five Schiff bases derived from diaminomaleonitrile (DAMN) and 2-hydroxy carbonyl compounds was performed using 1H, 13C and 15N NMR methods in solution and in the solid state as well. ATR-FTIR and X-Ray spectroscopies were used for confirmation of the results obtained by NMR method. The imine obtained from DAMN and benzaldehyde was synthesized as a model compound which lacks intramolecular hydrogen bond. Deprotonation of all synthesized compounds was done by treating with tetramethylguanidine (TMG). NMR data revealed that salicylidene Schiff bases in DMSO solution exist as OH forms without intramolecular hydrogen bonds and independent on the substituents in aromatic ring. In the case of 2-hydroxy naphthyl derivative, the OH proton is engaged into weak intramolecular hydrogen bond. Two of imines (salDAMN and 5-BrsalDAMN) exist in DMSO solution as equilibrium mixtures of two isomers (A and B). The structures of equilibrium mixture in the solid state have been studied by NMR, ATR-FTIR and X-Ray methods. The deprotonation of three studied compounds (salDAMN, 5-BrsalDAMN, and 5-CH3salDAMN) proceeded in two different ways: deprotonation of oxygen atom (X form) or of nitrogen atom of free primary amine group of DAMN moiety (Y form). For 5-NO2salDAMN and naphDAMN only one form (X) was observed.

Cellulose-SO3H as a biodegradable solid acid catalyzed one-pot three-component Ugi reaction: Synthesis of α-amino amide, 3,4-dihydroquinoxalin-2-amine, 4H-benzo[b][1,4]thiazin-2-amine and 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives

A variety of amines has become utilized in the three-compound Ugi reaction and synthesis of 3,4-dihydroquinoxalin-2-amine, 4H-benzo[b][1,4]thiazin-2-amine and 1,6-dihydropyrazine-2,3-dicarbonitrile derivatives in the presence of cellulose sulfuric acid as

Synthesis and Tritium Radiolabelling of Fluorinated Analogues of myo-Inositol

Syntheses have been developed for a set of six myo-inositol analogues from myo-inositol in which single hydroxy groups have been replaced by fluorine (monodeoxy-fluoro-myo-inositols).Except for 2-deoxy-2-fluoro-myo-inositol 32 and 1D-4-deoxy-4-fluoro-myo-