56037-30-0

Basic information

• Product Name: [1-Methyl-hex-(E)-ylidene]-phenyl-amine
• CAS NO: 56037-30-0
• Molecular Weight: 189.301
• Mol File: 56037-30-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [1-Methyl-hex-(E)-ylidene]-phenyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: [1-Methyl-hex-(E)-ylidene]-phenyl-amine(56037-30-0)
• EPA Substance Registry System: [1-Methyl-hex-(E)-ylidene]-phenyl-amine(56037-30-0)

Safety Data

• Hazardous Substances Data: 56037-30-0(Hazardous Substances Data)

Upstream product

• 628-71-7 1-Heptyne 
• 62-53-3 aniline 
• 67915-63-3 N-(1-methylhexyl)aniline 
• 60-29-7 diethyl ether 
• 7637-07-2 boron trifluoride 
• 110-43-0 n-pentyl methyl ketone 

Downstream Products

• 67915-63-3 N-(1-methylhexyl)aniline 

Relevant articles and documents

Heterogeneous intermolecular hydroamination of terminal alkynes with aromatic amines

Heterogeneous intermolecular hydroamination of alkynes with aromatic amines using inexpensive transition metal-exchanged clay catalysts was investigated. Reaction of terminal alkynes with aromatic amines gave higher yields of imines.

Enantioselective organocatalytic reductive amination of aliphatic ketones by benzothiazoline as hydrogen donor

The chiral phosphoric acid-catalyzed enantioselective reductive amination of aliphatic ketones with aromatic amines was successfully achieved by the use of benzothiazoline as the hydrogen donor. Corresponding chiral aliphatic amines were obtained with exc

Efficient ruthenium-catalyzed aerobic oxidation of amines by using a biomimetic coupled catalytic system

Efficient aerobic oxidation of amines was developed by the use of a biomimetic coupled catalytic system involving a ruthenium-induced dehydrogenation. The principle for this aerobic oxidation is that the electron transfer from the amine to molecular oxygen occurs stepwise via coupled redox systems and this leads to a low-energy electron transfer. A substrate-selective ruthenium catalyst dehydrogenates the amine and the hydrogen atoms abstracted are transported to an electron-rich quinone (2a). The hydroquinone thus formed is subsequently reoxidized by air with the aid of an oxygen-activating [Co(salen)]-type complex (27). The reaction can be used for the preparation of ketimines and aldimines in good to high yields from the appropriate corresponding amines. The reaction proceeds with high selectivity, and the catalytic system tolerates air without being deactivated. The rate of the dehydrogenation was studied by using quinone 2a as the terminal oxidant. A catalytic cycle in which the amine promotes the dissociation of the dimeric catalyst 1 is presented.