56077-27-1

Basic information

• Product Name: Ethanone, 1-(1-bromocyclohexyl)-
• CAS NO: 56077-27-1
• Molecular Formula: C8H13BrO
• Molecular Weight: 205.095
• Mol File: 56077-27-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(1-bromocyclohexyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(1-bromocyclohexyl)-(56077-27-1)
• EPA Substance Registry System: Ethanone, 1-(1-bromocyclohexyl)-(56077-27-1)

Safety Data

• Hazardous Substances Data: 56077-27-1(Hazardous Substances Data)

Upstream product

• 61997-71-5 2-benzenesulfonyl-2-methyl-1-oxa-spiro[2.5]octane 
• 92729-26-5 (1-Cyclohexyl-aethyl)-benzyl-aether 
• 108-94-1 cyclohexanone 
• 7789-69-7 phosphorus pentabromide 
• 823-76-7 Cyclohexyl methyl ketone 
• 7726-95-6 bromine 

Downstream Products

• 825-04-7 methyl 1-methylcyclohexanecarboxylate 
• 1123-27-9 1-(1-hydroxycyclohexyl)ethan-1-one 
• 108420-31-1 1-(1-mercapto-cyclohexyl)-ethanone 
• 1123-25-7 1-methyl-1-cyclohexanecarboxylic acid 
• 50993-21-0 1-methyl-N-phenylcyclohexane-1-carboxamide 
• 112383-63-8 1-(1-methylsulfanyl-cyclohexyl)-ethanone 

Relevant articles and documents

Iron-Catalyzed Acyl Migration of Tertiary α-Azidyl Ketones: Synthetic Approach toward Enamides and Isoquinolones

This paper reports that tertiary α-azidyl phenyl ketones can be transformed into enamides by treatment with FeBr2 at elevated temperature in DMF. The reaction proceeds via 1,2-benzoyl migration from α-carbon to the nitrogen atom, accompanied by expulsion of a nitrogen molecule. This protocol is suitable for the synthesis of N-(cyclopent-1-en-1-yl)benzamides, N-(cyclohex-1-en-1-yl)benzamides, and N-benzoyl-α-methyl enamines and provides a convenient approach toward isoquinolones.

Preparation stereoselective de methyle cetones α-bromees: stereochimie de l'addition d'anions en α d'un groupe sulfone sur des cyclohexanones monocycliques et steroidiques

This work describes stereochemical results obtained for the preparation of α-bromomethyl ketones or α-bromoaldehydes starting from monocyclic and steroid cyclohexanones, using the Durst method.In all the cases studied here, the bromine is introduced selectively in the equatorial position.However, for monocyclic compounds, the yields of α-bromocarbonyl compounds are limited by the competitive formation of α-ethylenic carbonyl compounds.