56366-43-9Relevant articles and documents
(1-Nosyl-5-nitroindol-3-yl)methyl ester: A novel protective group for carboxylic acids
Nishimura, Takuya,Yamada, Kouhei,Takebe, Tohru,Yokoshima, Satoshi,Fukuyama, Tohru
scheme or table, p. 2601 - 2604 (2009/05/26)
(Chemical Equation Presented) The usefulness of (1-nosyl-5-nitroindol-3-yl) methyl esters as a novel protective group for carboxylic acid is fully demonstrated. The novel protective group is stable under a broad range of conditions and can easily be deprotected under the mild conditions used for removal of the nosyl (Ns) group. It is orthogonal to the existing protective groups for carboxylic acids such as t-butyl and allyl esters.
1-and 2-azafulvenes
Barcock,Moorcroft,Storr,Young,Fuller
, p. 1187 - 1190 (2007/10/02)
Flash pyrolysis of dialkylaminopyrroles and thermolysis of 2-pyrrylmethyl phenyl sulfoxide at 65°C in solution gave azafulvenes which were trapped with a variety of nucleophiles.
FREE RADICAL REACTIONS INITIATED BY ORGANOCOBALT COMPLEXES. A NEW METHOD FOR THE DEGRADATION OF CARBOXYLIC ACIDS TO FUNCTIONALISED NOR-ALKANES VIA ACYLCOBALT SALOPHEN INTERMEDIATES.
Patel, Vinod F.,Pattenden, Gerald
, p. 707 - 710 (2007/10/02)
Arylmethyl- and allyl-acylcobalt salophens, undergo facile C-Co bond homolysis and in situ decarbonylation, producing new (alkyl) radical centres which can be intercepted with oxygen, nitrogen, halogen, sulphur and selenium containing radical trapping agents, leading to functionalised nor-alkanes (Scheme).
