56533-57-4Relevant articles and documents
-Methyl Functionalization of Electron-Poor Heterocycles: Free Radical Chlorination
Newkome, George R.,Kiefer, Garry E.,Yuan-Jiao Xia,Gupta, Vinod K.
, p. 676 - 679 (2007/10/02)
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SEQUENCE OF REPLACEMENT OF HYDROGEN IN 2,6-DIMETHYLPYRIDINE BY LITHIUM OR HALOGEN
Karpman, Ya.S.,Azimov, V.A.,Anisimova, O.S.,Yakhontov, L.N.
, p. 89 - 93 (2007/10/02)
It is shown that, according to the results of chromatographic mass spectrometry, the reaction of 2,6-dimethylpyridine with phenyllithium leads only to the monolithium derivative.The chlorination and bromination of 2,6-dimethylpyridine with various reagents were studied systematically.A method for the conversion of 2,6-bis(chloromethyl)pyridine to 2,6-bis(hydroxymethyl)pyridine is given.