56540-06-8

Basic information

• Product Name: ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE
• Synonyms: ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE;2,4-diketo-6-phenyl-cyclohexane-1-carboxylic acid ethyl ester;2,4-dioxo-6-phenyl-1-cyclohexanecarboxylic acid ethyl ester;ethyl 2,4-dioxo-6-phenyl-cyclohexane-1-carboxylate;ethyl 2,4-dioxo-6-phenylcyclohexane-1-carboxylate
• CAS NO: 56540-06-8
• Molecular Formula: C₁₅H₁₆O₄
• Molecular Weight: 259.2772
• Mol File: 56540-06-8.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE(56540-06-8)
• EPA Substance Registry System: ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE(56540-06-8)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 56540-06-8(Hazardous Substances Data)

Usage

General Description

Ethyl 2,4-dioxo-6-phenylcyclohexane-carboxylate is a chemical compound with the molecular formula C14H14O4. It is an ester of 6-phenyl-2,4-dioxo-cyclohexanecarboxylic acid and ethyl alcohol. ETHYL2,4-DIOXO-6-PHENYLCYCLOHEXANE- CARBOXYLATE is commonly used in the synthesis of organic compounds and in pharmaceutical research. It is important to handle ethyl 2,4-dioxo-6-phenylcyclohexane-carboxylate with care, as it may be harmful if swallowed, inhaled, or comes into contact with skin. Additionally, it may cause irritation to the eyes and skin.

Upstream product

• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 1007476-32-5 sodium ethyl acetylacetate enolate 
• 996-82-7 sodium diethylmalonate 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 105-53-3 diethyl malonate 
• 141-97-9 ethyl acetoacetate 
• 4192-77-2 ethyl cinnamate 

Downstream Products

• 39853-62-8 4-oxo-2-phenyl-2,3,4,10-tetrahydro-1H-phenothiazine-1-carboxylic acid ethyl ester 
• 93394-60-6 ethyl 3-benzyl-6,9-dioxo-8-phenyl-3-azabicyclo<3.3.1.>nonane-1-carboxylate 
• 6049-47-4 5-oxo-3-phenylhexanoic acid 
• 493-72-1 5-phenyl-cyclohexane-1,3-dione 
• 124-38-9 carbon dioxide 

Relevant articles and documents

Construction of Multiple-Substituted Chiral Cyclohexanes through Hydrogenative Desymmetrization of 2,2,5-Trisubstituted 1,3-Cyclohexanediones

The construction of chiral multiple-substituted cyclohexanes motifs is a challenging topic in organic synthesis. By the combination of desymmetrization and remote stereocontrol, a ruthenium-catalyzed transfer hydrogenative desymmetrization of 2,2,5-trisubstituted 1,3-cyclohexanediones has been successfully developed for the construction of chiral multiple-substituted cyclohexanes with high enantioselectivity and diastereoselectivity. When an ester group was introduced to the two-position, a hydrogenative desymmetrization/transesterification cascade occurred, affording the bicyclic lactones bearing three stereocenters, including two discrete stereocenters and one quaternary stereogenic center, with high enantioselectivity. The products are the multiple-substituted chiral cyclohexanes bearing the hydroxyl and carbonyl functional groups, which provide a new opportunity for further precise elaboration.