56542-90-6

Basic information

• Product Name: N-(furan-2-ylmethyl)-1,1-diphenylmethanimine
• Synonyms: N-(furan-2-ylmethyl)-1,1-diphenylmethanimine
• CAS NO: 56542-90-6
• Molecular Weight: 261.323
• Mol File: 56542-90-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(furan-2-ylmethyl)-1,1-diphenylmethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(furan-2-ylmethyl)-1,1-diphenylmethanimine(56542-90-6)
• EPA Substance Registry System: N-(furan-2-ylmethyl)-1,1-diphenylmethanimine(56542-90-6)

Safety Data

• Hazardous Substances Data: 56542-90-6(Hazardous Substances Data)

Upstream product

• 5267-34-5 aminodiphenylmethane hydrochloride 
• 54220-18-7 N-furfurylidene-1,1-diphenylmethylamine 
• 119-61-9 benzophenone 
• 1013-88-3 Benzophenone imine 
• 617-89-0 furan-2-ylmethanamine 
• 91-00-9 Benzhydrylamine 
• 98-01-1 furfural 
• 330455-50-0 N-[(1E)-2-furylmethylene]-1,1-diphenylmethanamine 

Downstream Products

• 617-89-0 furan-2-ylmethanamine 
• 125812-09-1 4-(Benzhydrylidene-amino)-3-(4-chloro-phenyl)-4-furan-2-yl-1-phenyl-butan-1-one 
• 548761-61-1 N-[4-(tert-butyl(diphenyl)silanyloxy)-1-(furan-2-yl)butyl]-4-methylbenzenesulfonamide 
• 548761-73-5 4-(tert-butyl(diphenyl)silanyloxy)-1-(furan-2-yl)butylamine 
• 125812-12-6 4-(Benzhydrylidene-amino)-3-(4-dimethylamino-phenyl)-4-furan-2-yl-1-phenyl-butan-1-one 

Relevant articles and documents

Benzhydrylamine: An effective aminating agent for the synthesis of primary amines

Aldehydes, ketones, alkyl toluene-p-sulfonates and halides are converted into the corresponding primary amines with benzhydrylamine as a valuable ammonia synthon in moderate to excellent yields.

Diastereoselective and Enantiospecific Synthesis of 1,3-Diamines via 2-Azaallyl Anion Benzylic Ring-Opening of Aziridines

The 1,3-diamine motif appears in numerous complex molecules, yet there are few methods for the stereoselective construction of this moiety. Herein, we demonstrate a stereocontrolled synthesis of 1,3-diamines, which bear up to three contiguous stereogenic centers, through benzylic ring-opening of aziridines with 2-azaallyl anion nucleophiles. Reactions proceed efficiently (yield up to 95%), diastereoselectively (dr up to >20:1), site selectively, and enantiospecifically to deliver products with differentiated amino groups.