56598-35-7Relevant articles and documents
Efficient nickel-catalyzed phosphinylation of C-S bonds forming C-P bonds
Yang, Jia,Xiao, Jing,Chen, Tieqiao,Yin, Shuang-Feng,Han, Li-Biao
supporting information, p. 12233 - 12236 (2016/10/21)
The first nickel-catalyzed phosphinylation of C-S bonds forming C-P bonds is developed. This transformation can proceed readily with the simple Ni(cod)2 at a loading down to 0.1 mol% at the 10 mmol scale. A variety of aryl sulfur compounds, i.e. sulfides, sulfoxides and sulfones all couple with P(O)-H compounds to produce the corresponding organophosphorus compounds in high yields, which provides an efficient new method for the construction of C-P bonds.
Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross-Coupling
Yang, Jia,Xiao, Jing,Chen, Tieqiao,Han, Li-Biao
, p. 3911 - 3916 (2016/05/24)
An efficient nickel-catalyzed phosphorylation of phenol derivatives with P(O)-H compounds via C-O/P-H cross-coupling is described. Under the reaction conditions, various phenyl pivalates coupled readily with hydrogen phosphoryl compounds to afford the corresponding coupling products aryl phosphonates and aryl phosphine oxides in good to high yields.
Nickel-catalysed P-C bond formation via P-H/C-CN cross coupling reactions
Zhang, Ji-Shu,Chen, Tieqiao,Yang, Jia,Han, Li-Biao
supporting information, p. 7540 - 7542 (2015/05/04)
Nickel-catalysed P-H/C-CN cross coupling reactions take place efficiently under mild reaction conditions affording the corresponding sp2C-P bonds. This transformation provides a convenient method for the preparation of arylphosphines and arylphosphine oxides from the readily available P-H compounds and arylnitriles. This journal is