5661-91-6

Basic information

• Product Name: 1(2H)-Azocinecarboxaldehyde, hexahydro- (8CI,9CI)
• Synonyms: 1(2H)-Azocinecarboxaldehyde, hexahydro- (8CI,9CI)
• CAS NO: 5661-91-6
• Molecular Formula: C8H15NO
• Molecular Weight: 141.2108
• Product Categories: ALDEHYDE
• Mol File: 5661-91-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1(2H)-Azocinecarboxaldehyde, hexahydro- (8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1(2H)-Azocinecarboxaldehyde, hexahydro- (8CI,9CI)(5661-91-6)
• EPA Substance Registry System: 1(2H)-Azocinecarboxaldehyde, hexahydro- (8CI,9CI)(5661-91-6)

Safety Data

• Hazardous Substances Data: 5661-91-6(Hazardous Substances Data)

Usage

Description

1(2H)-Azocinecarboxaldehyde, hexahydro(8CI,9CI) is a chemical compound characterized by the molecular formula C7H11NO. It features a six-membered azocine ring with a reactive aldehyde group, making it a potential building block for the synthesis of more complex molecules. Due to its reactivity, it is crucial to handle this compound with caution to avoid potential hazards.

Uses

Used in Organic Synthesis:
1(2H)-Azocinecarboxaldehyde, hexahydro(8CI,9CI) is used as a building block in organic synthesis for the creation of more complex molecules. Its reactive aldehyde group allows for various chemical reactions, making it a valuable component in the development of novel compounds.
Further Research:
As the specific uses and potential applications of 1(2H)-Azocinecarboxaldehyde, hexahydro(8CI,9CI) in different industries are not explicitly detailed in the provided materials, additional research may be necessary to fully understand its capabilities and potential impact across various sectors.

Upstream product

• 1121-92-2 heptamethyleneimine 
• 75-87-6 chloral 
• 201230-82-2 carbon monoxide 
• 109-94-4 formic acid ethyl ester 
• 502-42-1 cycloheptanone 
• 124-38-9 carbon dioxide 
• 673-66-5 7-amino-heptanoic acid lactam 

Downstream Products

• 145291-06-1 {(C₄H₂NC(C₆H₅))3(C₄HN(CH₂N(CH₂)7)C(C₆H₅))Cu} 
• 99875-27-1 1-formyloctahydroazocin-2-one 
• 19719-81-4 N-methylheptamethyleneimine 

Relevant articles and documents

Copper-diphosphine complex catalysts for N-formylation of amines under 1 atm of carbon dioxide with polymethylhydrosiloxane

N-formylation of a wide range of amines proceeded using copper-diphosphine complexes as homogeneous catalysts with polymethylhydrosiloxane (PMHS) under 1 atm of CO2. In the reaction of piperidine, for example, the turnover number (TON) reached 11700 in 23 h with 90% yield of the formylated product. This TON value is much higher than those of the reported catalysts for the formylation of amines under 1 atm of CO2 with hydrosilanes. The Cu complexes with phosphines having ortho-phenylene structures acted as good ligands for the formylation, as compared to a bidentate ligand connected with a propyl chain and a monodentate ligand. Among these diphosphines, ligands with alkyl functionalities, such as isopropyl and cyclohexyl groups, produced better results than the phenyl group. Not only cyclic secondary amines, but also linear secondary amines and aromatic and aliphatic primary amines were found to be reactive substrates. In the case of 2,2,6,6-tetramethylpiperidin-4-amine, the formylation proceeded regioselectively. A catalytic reaction pathway was proposed from a separate experiment using [Me2NCO2] [Me2NH2]. The Royal Society of Chemistry 2013.

Silver(I)-catalyzed Oxidation of Cyclic Secondary Amines with Peroxodisulphate

Oxidation of Piperidines, pyrrolidine, azetidine, perhydroazepine, and perhydroazocine with aqueous alkaline sodium peroxodisulphate in the presence of silver nitrate gave 1,1'-bipiperidines, a trimer of 1-pyrroline, 1,1'-biazetidine, 1,1'-biperhydroazepine together with 1-formylperhydroazepine, and 1-formylperhydroazocine, respectively.