56613-17-3

Basic information

• Product Name: Silane, trimethyl[(1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl)oxy]-
• CAS NO: 56613-17-3
• Molecular Formula: C13H24OSi
• Molecular Weight: 224.418
• Mol File: 56613-17-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[(1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl)oxy]-(56613-17-3)
• EPA Substance Registry System: Silane, trimethyl[(1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl)oxy]-(56613-17-3)

Safety Data

• Hazardous Substances Data: 56613-17-3(Hazardous Substances Data)

Upstream product

• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 75-77-4 chloro-trimethyl-silane 
• 76-29-9 3-bromocamphor 

Downstream Products

• 126256-26-6 phenyl camphor-3-carboxylate 
• 31658-22-7 exo-3-acetoxycamphor 
• 301-04-2 lead acetate 
• 2243-88-1 3-nitrocamphor 
• 21488-68-6 (1R)-3exo-hydroxy-bornan-2-one 
• 22759-33-7 3-exo-hydroxycamphor 
• 517-25-9 trinitromethane 
• 15051-75-9 3-hydroxymethylenecamphor 
• 76-29-9 endo-3-bromocamphor 
• 55922-56-0 (1S,3R,4R)-3-Benzenesulfinyl-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 

Relevant articles and documents

Active Metals from Potassium-Graphite. Iron-Graphite as a New Debrominating Agent of vic-Dibromoalkanes and of α-Bromo Ketones

Iron-graphite (Fe-Gr), easily prepared by reduction of FeCl3 with potassium-graphite (C8K) in tetrahydrofuran, is conveniently used for the stereospecific debromination of vic-dibromoalkanes to alkenes and for the reductive debromination of α-bromo ketones to ketones in high yields.The latter reaction proceeds via Fe(II) enolates, which undergo deuteration, condensation, or O-silylation by reaction respectively with D2O, heptanal, or chlorotrimethylsilane.Moreover, the reaction of α,α'-dibromo ketones with Fe-Gr leads to 2-oxyallyl cations which can be trapped by suitable electron-rich olefins (enamines) or dienes (furan).