5665-75-8Relevant articles and documents
Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions
Chen, Liang-An,Lear, Alan R.,Gao, Pin,Brown, M. Kevin
supporting information, p. 10956 - 10960 (2019/07/08)
A method for the construction of boron-substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2-disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.
Application of LB-Phos·HBF4 in the Suzuki coupling reaction of 2-bromoalken-3-ols with alkylboronic acids
Guo, Binjie,Fu, Chunling,Ma, Shengming
experimental part, p. 4034 - 4041 (2012/08/29)
LB-Phos·HBF4 was used in the Suzuki coupling reaction of 2-bromoalken-3-ols with alkylboronic acids to give the coupling products in moderate to good yields. Substituents such as benzyl, phenyl, allyl, and alkyl are tolerated at the 1-and 3-pos
Allyl alcohols and organocerium reagents, II. - Mechanism and extensibility of the reaction
Bartoli, Giuseppe,Bellucci, M. Cristina,Bosco, Marcella,Dalpozzo, Renato,De Nino, Antonio,Sambri, Letizia,Tagarelli, Antonio
, p. 99 - 104 (2007/10/03)
Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.