5676-58-4Relevant articles and documents
Metal free montmorillonite KSF clay catalyzed practical synthesis of benzoxazoles and benzothiazoles under aerobic conditions
Kummari, Vijaya Babu,Chiranjeevi, Kalavakuntla,Suman Kumar, Alleni,Kumar, Rathod Aravind,Yadav, Jhillu Singh
supporting information, p. 3335 - 3342 (2019/11/11)
An efficient method for the synthesis of benzoxazoles and benzothiazoles via montmorillonite KSF clay catalyzed condensation reaction between 2-aminophenols or 2-aminothiophenols and β-diketones is reported. The efficiency of the reaction reflects from the wide substrate scope with electronic differentiation on aryls. The reaction is metal free and proceeds without the exclusion of air or moisture, and further the catalyst can be recycled up to 3–5 catalytic cycles.
Eco-friendly syntheses of 2-substituted benzoxazoles and 2-substituted benzothiazoles from 2-aminophenols, 2-aminothiophenols and DMF derivatives in the presence of imidazolium chloride
Tian, Qingqiang,Luo, Wen,Gan, Zongjie,Li, Dan,Dai, Zeshu,Wang, Huajun,Wang, Xuetong,Yuan, Jianyong
supporting information, (2019/01/21)
A simple, economical and metal-free approach to the synthesis of 2-substituted benzoxazoles and 2-substituted benzothiazoles from 2-aminophenols, 2-aminothiophenols and DMF derivatives, only using imidazolium chloride (50% mmol) as promoter without any other additive, was reported. Various 2-substituted benzoxazoles and 2-substituted benzothiazoles were thus prepared in moderate to excellent yields.
Multicatalytic Beckmann rearrangement of 2-hydroxylarylketone oxime: Switchable synthesis of benzo[d]oxazoles and N-(2-hydroxylaryl)amides
Li, Zhen,Fang, Chengtao,Zheng, Yannan,Qiu, Guanyinsheng,Li, Xiaofang,Zhou, Hongwei
, p. 3934 - 3937 (2018/10/02)
A switchable synthesis route is developed for benzo[d]oxazole derivatives and (2-hydroxylaryl)benzamide from 2-hydroxylbenzeneketoxime using organomolecules (BOP-Cl, and CNC) and Lewis acid cocatalyzed Beckmann rearrangement (BR) reaction. Further, this reaction is switched using different organocatalysts.